Scopus İndeksli Yayınlar Koleksiyonu
Permanent URI for this collectionhttps://hdl.handle.net/20.500.12573/395
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Article Citation - WoS: 3Citation - Scopus: 4The Experimental Determination of Thermophysical Properties of Intermetallic CuAl2 Phase in Equilibrium With (Al Plus Cu Plus Si) Liquid(Academic Press Ltd- Elsevier Science Ltd, 2016-06) Altintas, Yemliha; Aksoz, Sezen; Keslioglu, Kazim; Marasli, Necmettin; Keşlioʇlu, KâzImThe equilibrated grain boundary groove shapes of solid CuAl2 in equilibrium with (Al + Cu + Si) eutectic liquid were observed from a quenched sample by using a radial heat flow apparatus. The Gibbs-Thomson coefficient, (solid + liquid) interfacial energy and grain boundary energy of the solid CuAl2 were determined from these observed shapes. The thermal conductivity of the eutectic solid and the thermal conductivity ratio of eutectic liquid to the eutectic solid in the (Al + 26.82 wt.% Cu + 5.27 wt.% Si) eutectic alloy at its eutectic melting temperature were also measured with a radial heat flow apparatus and a Bridgman-type growth apparatus, respectively. The three phases of (Al + Cu + Si) alloy have detected as Al solution, Si and theta (CuAl2) phases with EDX composition analysis and the microstructure of these phases were photographed by SEM. (C) 2016 Elsevier Ltd. All rights reserved.Article Citation - WoS: 35Citation - Scopus: 29Microstructural Analysis of Low-Calcium Fly Ash-Based Geopolymer Concrete With Different Ratios of Activator and Binder Under High Temperatures(Springer Heidelberg, 2024-06-25) Kucukgoncu, Hurmet; Ozbayrak, AhmetGeopolymer concretes have emerged as an alternative to traditional Portland cement concretes with high strength, good durability, well corrosion performance and high-temperature resistance, and being a sustainable and environmentally friendly material. In this study, a comprehensive microstructural analysis of low-calcium fly ash-based geopolymer concrete samples with different alkali activator to binder ratios was conducted after exposure to temperatures ranging from 400 to 800 degrees C. The experimental results of the geopolymer concrete specimens found out significant findings, including a notable loss of mass and an approximate 80% decrease in compressive strength after exposure to 800 degrees C. The microstructural analysis underlined crack formation, voids and porosities in the geopolymer matrix at elevated temperatures, affecting the physical and mechanical properties of the material. The study presents significant insights into the behaviour of low-calcium fly ash-based geopolymer concrete with different binder and alkali activator ratios under high temperatures, revealing the performance of geopolymer concretes in extreme environments and the effect of incompatibility between geopolymer concrete and aggregate due to thermal temperature effects on this performance.Article Citation - WoS: 4Citation - Scopus: 4Investigations of Electrical Resistivity and Thermal Conductivity Dependences on Growth Rate in the Al-Cu Eutectic Alloy(Springer/plenum Publishers, 2021-05-03) Marasli, Necmettin; Bayram, UmitDirectional solidification of Al-Cu-Ti (Al-33wt%Cu-0.1wt%Ti) eutectic alloy was done with a growth rate range (V = 8.58 to 2038.65 mu m.s(-1)) at a temperature gradient of 6.45 K.mm(-1) using Bridgman-type directional solidification furnace. The measurements of thermal conductivity (K) and electrical resistivity (rho) for the Al-Cu-Ti alloy solidified with the different values of V were made by the longitudinal heat flow method (LHFM) and DC four-point probe technique (FPPT). While the highest values of K and rho were determined to be 236.04 W.K-1.m(-1) and 5.91 x 10(-8) omega m, respectively, at 8.58 mu m.s(-1), the lowest values of K and rho were obtained to be 199.82 W.K-1.m(-1) and 12.11 x 10(-8) omega m, respectively, at 2038.65 mu m.s(-1). The K and rho dependences on V were obtained to be K=259.96xV(-0.032) and rho=4.47x10(-8)V(0.13) from linear regression analysis. The fusion enthalpy ( increment H) and specific heat difference between solid and liquid ( increment C-P) for the Al-Cu-Ti were also determined to be 222.69 J.g(-1) and 0.266 Jg(-1).K-1, respectively, by means of differential scanning calorimetry (DSC).Article Citation - WoS: 28Citation - Scopus: 30Effect of Construction and Demolition Waste on the Long-Term Geo-Environmental Behaviour of Cemented Paste Backfill(Springer, 2021-05-05) Yilmaz, T.; Ercikdi, B.The construction and demolition waste (CDW) could be used as backfill material to fill the voids created during the ore production in underground mining. However, there is a need to clarify the impact of CDW on groundwater pollution when it is used as backfill material in cemented paste backfill (CPB) of sulphide-rich tailings (S-rT). This study presents the influence of CDW on the long-term geo-environmental behaviour of CPB samples (CPBs) when used as replacement (10 wt.%) to S-rT. For this reason, the dynamic-tank leaching test was conducted on CPBs and pH, conductivity (Ec), sulphate (SO42-) and heavy metals (HMs) analyses were executed for leachates over 30-360 days of leaching period. The effects of mineralogy and microstructure on the geo-environmental behaviour of CPBs were also analysed via X-ray fluorescence (XRD) and mercury intrusion porosimeter (MIP). The utilisation of CDW in CPB mixtures was found to reduce the SO42- release (up to 13.89%), neutralise the acid generated and lower the Ec (up to 22.16%). Furthermore, the HMs releases (except As, Cu and Zn) were prevented (Ni and Cr) or reduced up to 92%, which is compatible with the improved CPB microstructure. Only the release of arsenic (As) exceeded the limit value for groundwater in CPB of CDW leachate. These findings suggest that not only the cost, strength and stability but also the impact on groundwater pollution should be considered when disposing of CDW as CPB material in underground voids.