Scopus İndeksli Yayınlar Koleksiyonu
Permanent URI for this collectionhttps://hdl.handle.net/20.500.12573/395
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Article Citation - WoS: 125Citation - Scopus: 149Microstructure and Tribological Properties of TiTaHfNbZr High Entropy Alloy Coatings Deposited on Ti-6Al Substrates(Elsevier Sci Ltd, 2019-02) Tuten, N.; Canadinc, D.; Motallebzadeh, A.; Bal, B.We report on the microstructure and tribological behavior of equimolar TiTaHfNbZr high entropy alloy (HEA) thin films deposited on the biomedical Ti-6Al-4V substrates by RF magnetron sputtering. Results of nanoindentation and sliding wear experiments were evaluated along with the microstructure and topographical information obtained from scanning electron microscopy and atomic force microscopy. The findings clearly demonstrate that the TiTaHfNbZr HEA not only forms a homogenous and dense coating mechanically compatible with the Ti-6Al-4V substrates, but also provides a significantly enhanced surface protection against wear and cracking, which could prove valuable especially in long-term orthopedic implants that bear dynamic contact loading, such as in the cases of hip or knee joints.Article Citation - WoS: 39Citation - Scopus: 44Fracture Behavior of Novel Biomedical Ti-Based High Entropy Alloys Under Impact Loading(Elsevier Science SA, 2021-01) Gurel, S.; Yagci, M. B.; Canadinc, D.; Gerstein, G.; Bal, B.; Maier, H. J.This paper focuses on the mechanical properties and fracture behavior of newly developed body-centered-cubic structured TiTaHfNb, TiTaHfNbZr and TiTaHfMoZr high entropy alloys (HEAs) under impact loading as part of an effort to evaluate their potential utility as implant materials. The experimental findings showed all three Ti based HEAs have lower Young's modulus as compared to the conventionally used implant materials. Fractography analysis revealed that the TiTaHfNb HEA demonstrated significant ductility with the highest energy absorption capacity, while the TiTaHfNbZr and the TiTaHfMoZr alloys exhibited mixed mode fracture with relatively low ductility. Specifically, the reduction of ductility and energy absorption capacity under impact loading was attributed to the addition of Zr and Mo into Ti-based HEA system, which facilitates formation of additional dislocations in the microstructure due to increased lattice distortion. The current findings demonstrate that, from a mechanical point of view, the TiTaHfNb HEA could be considered as an alternative implant material for applications demanding high wear and corrosion resistance, such as hip or knee implants, and thus, warrant further investigation of the biomedical performance of this alloy.YArticle Citation - WoS: 102Citation - Scopus: 111Effect of Strain Rate on Hydrogen Embrittlement Susceptibility of Twinning-Induced Plasticity Steel Pre-Charged With High-Pressure Hydrogen Gas(Pergamon-Elsevier Science Ltd, 2016-09) Bal, B.; Koyama, M.; Gerstein, G.; Maier, H. J.; Tsuzaki, K.The effects of tensile strain rate on the hydrogen-induced mechanical and microstructural features of a twinning-induced plasticity (TWIP) steel were investigated using a Fe-23Mn-0.5C steel with a saturated amount of hydrogen. To obtain a homogeneous hydrogen distribution, high-pressure hydrogen gas pre-charging was performed at 423 K. Similar to previous studies on hydrogen embrittlement, the deterioration in the tensile properties became distinct when the strain rate was decreased from 0.6 x 10(-3) to 0.6 x 10(-4) s(-1). In terms of microstructural features, hydrogen-precharging decreased the thickness of deformation twin plates, and it localized dislocation slip. Moreover, facets of the hydrogen induced quasi-cleavage feature on the fracture surface became smoother with decreasing strain rate. In this study, we proposed that a combined effect of hydrogen segregation, slip localization, and thinning of twin plates causes the hydrogen embrittlement of TWIP steels, particularly at a low strain rate. (C) 2016 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.Article Citation - WoS: 57Citation - Scopus: 62Corrosion Behavior of Novel Titanium-Based High Entropy Alloys Designed for Medical Implants(Elsevier Science SA, 2020-11) Gurel, S.; Yagci, M. B.; Bal, B.; Canadinc, D.This paper reports on the corrosion behavior of three TiTaHf-based high entropy alloys (HEAs) in simulated body fluid (SBF) and artificial saliva (AS) in order to assess their potential utility as implant materials. Specifically, TiTaHfNb, TiTaHfNbZr and TiTaHfMoZr HEAs were subjected to static immersion experiments in SBF and AS, and both the surfaces of the samples and the immersion fluids were thoroughly examined with the state of the art techniques. The experimental results presented herein revealed that the presence of Zr and Nb in the TiTaHf-based samples enhanced corrosion performance with reduced ion release and better surface properties, while Mo addition resulted in an inhomogeneous microstructure, leading to dendrite structures and significant amount of ion release upon immersion in both media. Furthermore, a protective passive layer formation or crystallization was present on all HEA surfaces, implying that corrosion resistance can be sustained in long-term applications. Overall, the set of findings presented herein constitute an early indication of the potential of the TiTaHf-based HEAs to be utilized as implant materials.Article Citation - WoS: 36Citation - Scopus: 40Assessment of Biocompatibility of Novel TiTaHf-Based High Entropy Alloys for Utility in Orthopedic Implants(Elsevier Science SA, 2021-07) Gurel, S.; Nazarahari, A.; Canadinc, D.; Cabuk, H.; Bal, B.This paper presents the findings of experimentally observed corrosion response of novel TiTaHf-based high entropy alloys (HEAs) in fetal bovine serum (FBS) to evaluate their biocompatibility in presence of proteins and potential to be used as implant materials. Particularly, TiTaHfNb, TiTaHfNbZr and TiTaHfMoZr HEAs were subjected to static immersion experiments in FBS media, and both the HEA samples and the immersion fluids underwent thorough characterization. The findings presented herein show that Zr and Mo addition to the TiTaHf solid solution increased the total ion release from the resulting HEAs in FBS, while the TiTaHfNb HEA became prominent in terms of biocompatibility owing to the reduced ion release in FBS. Moreover, hydroxy apatite (HA) formation was evident on the surfaces of all three HEAs upon immersion in FBS, indicating the potential of the three TiTaHf-based HEAs to form desired binding with the human bone. Considering the fact that passive oxide layer formation facilitating lower susceptibility to corrosion in long-term applications was also observed in the studied HEAs, further elaboration on their mechanical and biological responses is warranted for the sake of a comprehensive assessment regarding their utility as orthopedic implant materials.