Symmetric Naphthalenediimidequaterthiophenes for Electropolymerized Electrochromic Thin Films

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Abstract

A new symmetric naphthalenediimidequaterthiophene (s-NDI2ODT4) was synthesized and exhibited the capability to electropolymerize alone or with EDOT affording polymers with controlled donor/acceptor monomer ratios. s-NDI2ODT4-EDOT-based copolymers showed low band gaps, wide optical absorption ranges extending to the near IR region, tuned electrical properties, thin-film surface morphology and hydrophilicity as well as high coloration efficiency in electrochromic devices.

Description

Ferrante, Francesco/0000-0002-2989-4365; Facchetti, Antonio/0000-0002-8175-7958; Cataldo, Sebastiano/0000-0002-4271-9641; Figa, Viviana/0000-0002-0290-2425; Usta, Hakan/0000-0002-0618-1979; Principato, Fabio/0000-0003-2787-0877

Keywords

Electrochromic materials, Thin films, Electropolymerization, Thiophenes

Fields of Science

02 engineering and technology, 0210 nano-technology, 01 natural sciences, 0104 chemical sciences

Citation

WoS Q

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OpenCitations Citation Count
29

Volume

3

Issue

23

Start Page

5985

End Page

5994