From 2-Methylimidazole to 1,2,3-Triazole: A Topological Transformation of ZIF-8 and ZIF-67 by Post-Synthetic Modification

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Abstract

Bridging ligand replacement in zeolitic imidazolate frameworks, ZIF-8 and ZIF-67, by 1,2,3-triazole was investigated. A complete substitution of 2-methylimidazole by 1,2,3-triazole resulted in a topological transformation of the parent framework from a sodalite (SOD) network to a diamond (DIA) network.

Description

Tam, Benjamin/0000-0002-8119-3996; Erkartal, Mustafa/0000-0002-9772-128X; Yazaydin, A. Ozgur/0000-0001-8562-723X; Erkilic, Ufuk/0000-0003-1849-9180; Sen, Unal/0000-0003-3736-5049; Usta, Hakan/0000-0002-0618-1979;

Keywords

METAL-ORGANIC FRAMEWORKS, ASSISTED LINKER EXCHANGE, ZEOLITIC IMIDAZOLATE FRAMEWORKS, DE-NOVO SYNTHESIS

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02 engineering and technology, 0210 nano-technology, 01 natural sciences, 0104 chemical sciences

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75

Volume

53

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12

Start Page

2028

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2031
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