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Permanent URI for this collectionhttps://hdl.handle.net/20.500.12573/395

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Subject: search.filters.subject.Supercapacitor

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  • Article
    Citation - WoS: 64
    Citation - Scopus: 58
    MoO3/WO3 as Electrode Material for Supercapacitor and Catalyst for Methanol and Ethanol Electrooxidation
    (Nature Portfolio, 2024-04-30) Askari, Mohammad Bagher; Salarizadeh, Parisa; Zadeh, Mohammad Hassan Ramezan; Ramezan zadeh, Mohammad Hassan
    The potential of metal oxides in electrochemical energy storage encouraged our research team to synthesize molybdenum oxide/tungsten oxide nanocomposites (MoO3/WO3) and their hybrid with reduced graphene oxide (rGO), in the form of MoO3/WO3/rGO as a substrate with relatively good electrical conductivity and suitable electrochemical active surface. In this context, we presented the electrochemical behavior of these nanocomposites as an electrode for supercapacitors and as a catalyst in the oxidation process of methanol/ethanol. Our engineered samples were characterized by X-ray diffraction pattern and scanning electron microscopy. As a result, MoO3/WO3 and MoO3/WO3/rGO indicated specific capacitances of 452 and 583 F/g and stability of 88.9% and 92.6% after 2000 consecutive GCD cycles, respectively. Also, MoO3/WO3 and MoO3/WO3/rGO nanocatalysts showed oxidation current densities of 117 and 170 mA/cm(2) at scan rate of 50 mV/s, and stability of 71 and 89%, respectively in chronoamperometry analysis, in the MOR process. Interestingly, in the ethanol oxidation process, corresponding oxidation current densities of 42 and 106 mA/cm(2) and stability values of 70 and 82% were achieved. MoO3/WO3 and MoO3/WO3/rGO can be attractive options paving the way for prospective alcohol-based fuel cells.
  • Article
    Citation - WoS: 17
    Citation - Scopus: 19
    Investigation of the Performance and Properties of ZnO/GO Double-Layer Supercapacitor
    (Pergamon-Elsevier Science Ltd, 2024-08) Buyukkurkcu, Handan; Durmus, Ali; Colak, Hakan; Kurban, Rifat; Sahmetlioglu, Ertugrul; Karakose, Ercan
    Composite electrode material was formed by mixing reduced graphene oxide (rGO) and zinc oxide (ZnO) compound, using the Hummers and green synthesis methods, respectively. Of rGO powder, 10 g was mixed with 10%, 20% and 30% ZnO, and composite electrodes were obtained by using 10% binder. The energy storage performance and structural characteristics of the supercapacitor were evaluated by analyzing the capacitance values of the synthesized electrodes. The structural characterization of ZnO/rGO composites was performed using X-ray diffraction and field-emission scanning electron microscopy. The electrochemical properties of the ZnO/GO electrodes were analyzed by cyclic voltammetry, electrochemical impedance and galvanostatic charge -discharge tests. The specific capacitance value of electrodes increased as zinc content increased in the ZnO/ rGO composite material used to produce electrodes. The maximum specific capacitance values were measured at 5 mV/s scanning rate as 194.23 (rGO), 366.81 (10% ZnO), 383.18 (20% ZnO) and 410.48 F/g (30% ZnO). In conclusion, the use of composite material formed by the combination of ZnO nanoparticles obtained by green synthesis method from orange peel and graphene oxide increased the electrochemical efficiency of the supercapacitor.