Scopus İndeksli Yayınlar Koleksiyonu

Permanent URI for this collectionhttps://hdl.handle.net/20.500.12573/395

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  • Article
    Citation - WoS: 8
    Citation - Scopus: 10
    Compatibility and Biomineralization Oriented Optimization of Nutrient Content in Nitrate-Reducing Microbial Self-Healing Concrete
    (MDPI, 2021-08-11) Kardogan, Beyza; Sekercioglu, Kadir; Ersan, Yusuf Cagatay
    Microbially induced calcium carbonate precipitation (MICP) can be mentioned among the popular approaches to develop a self-healing concrete. The production of dissolved inorganic carbon through microbial activity is the main precursor for MICP in concrete and it is limited by the bioavailability of the nutrients. When nutrients are added to the mortar as admixtures, their bioavailability becomes more significant for crack repair because nutrients disperse in the mortar and considerable fraction stays far from a single crack. Therefore, the determination of bioavailability of nutrients and its variation with the initial nutrient content and crack age is essential to optimize a recipe for bacteria-based self-healing concrete. This study presents the optimum nutrient content defined for nitrate-reduction-based self-healing bioconcrete. In the tests, calcium nitrate (CN) and calcium formate (CF) were combined with a CF:CN w/w ratio of 2.50. Mortar properties and bioavailability of nutrients were analysed at different nutrient doses. Moreover, the bioavailability of nutrients at different crack ages changing between 3 and 56 days was monitored. Finally, resuscitation, microbial activity and the MICP performance of nitrate reducing biogranules were tested at defined nutrient bioavailabilties. The optimum nutrient content was determined as 7.00% (CF 5.00% and CN 2.00%). The leaching rates of formate ions were twice the leaching rate of the nitrate ions at similar initial concentrations, which led to a bioavailable HCOO-/NO3-N ratio of 23 g/g in cracked mortar. Under optimum nutrient conditions, the CaCO3 precipitation yield of nitrate reducing biogranules was recorded as 1.5 g CaCO3/g HCOO- which corresponded to 68% C precipitation efficiency.
  • Article
    Citation - WoS: 8
    Citation - Scopus: 9
    A New Quantitative Welding Degree Classification for Ignimbrites
    (Springer, 2023-06-28) Akin, Mutluhan; Topal, Tamer; Dincer, Ismail; Akin, Muge K.; Ozvan, Ali; Orhan, Ahmet; Orhan, Ayse
    As a pyroclastic rock type, ignimbrites may reveal varying degrees of welding depending on the temperature (> 535 celcius) and overburden pressure conditions during its formation. The welding degree of ignimbrites increases as the formation temperature and the thickness of the overburden deposit in the depositional environment escalate, which are the most crucial factors controlling the rate of welding in ignimbrites. With the increasing temperature, plastic deformation is observed in ignimbrites and the glassy minerals are being welded. Furthermore, the thickness of the overburden causes the deformation of the ash matrix in ignimbrites at the lower sections and the pumice grains are flattened at different rates. An increase in the degree of welding of ignimbrites causes an improvement in the physical and mechanical properties of the rock material as well. Within the scope of this research, petrographical, mineralogical, and geochemical studies were carried out on a total of 16 different ignimbrite types, which have different color and texture properties, obtained from three different regions of Turkey (Kayseri, Nevsehir, Ahlat) where ignimbrites extensively crop out, and the physical and mechanical properties of these samples were revealed. Consequently, a new welding classification was developed for ignimbrites considering the uniaxial compressive strength and dry unit weight. The proposed welding classification consists of six classes ranging from non-welded to highly welded. When the welding degrees of the selected ignimbrites are evaluated, Kayseri ignimbrites mostly exhibit moderate welding characteristics. Nevsehir ignimbrites, on the other hand, have a low welding degree whereas the degree of welding in Ahlat ignimbrites may vary from low to high. Additionally, long and short axis lengths of pumice grains in the ignimbrite specimens were determined by measuring under the microscope, and shape ratios were determined by different shape parameter evaluation methods. As a result, it has been concluded that the pumice grains in Kayseri and Ahlat ignimbrites have a more lenticular structure than the pumice grains in Nevsehir ignimbrites. Eventually, the welding degree classes of ignimbrites and the classification developed by using threshold values of the oblateness ratio (OR) values of pumice grains at different welding degrees are quite compatible. The proposed welding degree classification is of great importance in the selection of ignimbrites widely used as dimension stone and in terms of engineering classification of this rock type as well as it will guide to the scientific studies to be performed on ignimbrites with varying physical and mechanical properties.