Scopus İndeksli Yayınlar Koleksiyonu
Permanent URI for this collectionhttps://hdl.handle.net/20.500.12573/395
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Article Citation - WoS: 25Citation - Scopus: 25Microwave-Assisted Green Approach for Graft Copolymerization of L-Lactic Acid Onto Starch(Wiley, 2015-10-15) Salimi, Kouroush; Topuzogullari, Murat; Dincer, Sevil; Aydin, Halil Murat; Piskin, ErhanPoly l-lactic acid grafted starch (St-g-PLA) copolymers were directly synthesized under microwave irradiation by using sodium hydroxide (NaOH) and stannous 2-ethyl hexanoate acting as a catalyst, without the use of toxic solvents. The product were characterized by Fourier transform infrared spectroscopy (FTIR), nuclear magnetic resonance (C-13 CP/MAS NMR), X-ray diffraction (XRD), scanning electron microscopy (SEM) and thermogravimetric analysis (TGA-DTG). SEM analysis indicated that microwave heating had a considerable effect on the interfacial adhesion between PLA and starch. Thermogravimetric analysis (TGA-DTG) revealed that copolymers exhibited better thermal stability. Maximum PLA grafting was achieved with the following reaction conditions: 450W microwave power, monomer ratio of 1:5 and 0.4M of NaOH. This study demonstrates that it is possible to obtain St-g-PLA copolymers with better processing characteristics and smaller sizes via microwave-assisted synthesis. The applied procedure is an interesting green synthesis method for the production of biodegradable materials used in a diverse range of applications. (c) 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016, 133, 42937.Article Citation - Scopus: 21Characterization of Local Sorghum (Sorghum Bicolor L.) Population Grains in Terms of Nutritional Properties and Evaluation by GT Biplot Approach(Wiley-VCH Verlag info@wiley-vch.de, 2020-02-03) Kaplan, Mahmut; Kale, Hasan; Kardeş, Yusuf Murat; Karaman, Kevser; Kahraman, Kevser; Yilmaz, Mehmet Fatih; Akar, TanerThis study is conducted to characterize some nutritional attributes and starch properties of 156 Turkish sorghum populations and 4 standard cultivars (Sorghum bicolor L.). Crude protein contents of the populations vary between 6.67% and 14.33%, digestible protein ratios between 6.67% and 82.24%, crude oil contents between 2.15% and 6.40%, phytic acid contents between 0.37% and 4.09%, resistant starch between 1.10% and 34.23%, nonresistant starch between 10.79% and 79.61%, total starch between 15.42% and 85.54%, amylose between 5.67% and 43.48%, amylopectin between 9.45% and 65.67%, total phenolic between 0.19% and 5.06 mg GAE/g and antiradical activity between 3.72% and 91.48%. Significant differences are obtained from starch-based Rapid Visco Analyzer parameters of sorghum genotypes. As compared standard cultivars, several superior genotypes are identified in terms of nutritional characteristics. Genotype treatment (GT) biplot analysis revealed ideal genotypes for investigated parameters. Present findings confirmed that there are many genotypes with superior nutritional properties in local sorghum genotypes. © 2020 Elsevier B.V., All rights reserved.