Scopus İndeksli Yayınlar Koleksiyonu

Permanent URI for this collectionhttps://hdl.handle.net/20.500.12573/395

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Subject: search.filters.subject.Recycle

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  • Article
    Citation - WoS: 23
    Citation - Scopus: 28
    Ultra-Rapid Catalytic Degradation of 4-Nitrophenol With Ionic Liquid Recoverable and Reusable Ibuprofen Derived Silver Nanoparticles
    (Elsevier Sci Ltd, 2018-06) Hassan, Syeda Sara; Carlson, Krista; Mohanty, Swomitra Kumar; Sirajuddin; Canlier, Ali
    This study reports a one-pot and eco-friendly method for the synthesis of spherical ibuprofen derived silver nanoparticles (IBU-AgNPs) in aqueous media using ibuprofen analgesics drug as capping as well as reducing agent. Formation of AgNPs occurred within a few min (less than 5 min) at room temperature without resorting to any harsh conditions and hazardous organic solvents. Synthesized AgNPs were characterized with common analytical techniques. Transmission electron microscope (TEM) images confirmed the formation of spherical particles having a size distribution in the range of 12.5 +/- 1.5 nm. Employment of IBU analgesic aided the control of better size distribution and prevented agglomeration of particles. Such AgNPs solution was highly stable for more than two months when stored at ambient temperature. The IBU-AgNPs solution showed excellent ultra-rapid catalytic activity for the complete degradation of toxic 4-nitrophenol (4-NPh) into non-toxic 4-aminophenol (4-APh) within 40 s. AgNPs were recovered with the help of water insoluble-room temperature ionic liquid and reused with enhanced catalytic potential. This method provides a novel, rapid and economical alternative for the treatment of toxic organic pollutants to maintain water quality and environmental safety against water pollution. It is extendable for the control of other reducible contaminants in water as well. Furthermore, this catalytic activity for an effective degradation of organic toxins is expected to play a crucial role for achieving the Sustainable Development Goal 6 set by United Nations. (C) 2017 Elsevier Ltd. All rights reserved.
  • Article
    Citation - WoS: 1
    Citation - Scopus: 1
    Investigation of Friction Coefficient Changes in Recycled Composite Materials Under Constant Load
    (MDPI, 2023-09-18) Gunes, Aydin; Duzcukoglu, Hayrettin; Salur, Emin; Aslan, Abdullah; Sahin, Omer Sinan
    The surface quality of machine elements may deteriorate over time while operating under different conditions. This deterioration adversely affects the wear behavior in the contact areas, and these materials become unusable over time. In machine elements especially, the heat transfer, wear amount and surface roughness parameters in the contact area are very important in order for the system to work efficiently. In order to understand this change, composite materials were produced by adding spheroidal graphite cast iron (GGG40) with high lubricating properties at different rates to bronze (CuSn10), which is widely used as a self-lubricating bearing material. In this study, four different mixing ratios (B60D40, B70D30, B80D20 and B90D10) and B100, which is completely produced from bronze chips, were used for comparison purposes. In addition, these produced composite materials were compared with pure CuSn10 and pure GGG40 via double-acting isostatic hot pressing, and then the results were examined. The composite materials were made at two different temperatures (400 degrees C and 450 degrees C) and three different pressures (480 MPa, 640 MPa and 820 MPa) using recycled waste chips. Composites produced by recycling waste chips both reduce costs and make a positive contribution to the natural environment. Thus, more advantageous self-lubricating bearing materials will be produced, and the efficiency will be increased in these materials. The time-dependent variation in the friction coefficient observed after the wear tests performed under constant load is explained, and the resulting surface structures are presented with SEM images and EDS analyses. After the wear tests, it was observed that the process parameters used in production effectively influenced the wear behavior. In particular, when the production pressure was low (480 MPa), the wear behavior was adversely affected because sufficient bonding between the chips could not be achieved. In addition, as the amount of GGG40 used as a reinforcement material increased, the spheroidal graphite contained in it positively affected the wear behavior. The lubricating effect provided by this spheroidal graphite reduced wear in the contact area and the friction coefficient.