Scopus İndeksli Yayınlar Koleksiyonu
Permanent URI for this collectionhttps://hdl.handle.net/20.500.12573/395
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Article Citation - WoS: 14Citation - Scopus: 14Isotherms, Kinetics and Thermodynamics of Pb(II) Adsorption by Crosslinked Chitosan/Sepiolite Composite(Springer, 2021-04-13) Senol-Arslan, DilekA novel composite adsorbent was prepared from chitosan (Ch) and sepiolite (S) for removal of Pb(II) from aqueous solution. The Ch-S composite beads were successfully synthesized by crosslinking epichlorohydrin (ECH) and tripolyphosphate (NaTPP). A number of physicochemical parameters such as, pH, initial Pb(II) concentration, temperature, contact time and desorption have been studied during the adsorption process. Experimental data acquired from batch adsorption tests have been analyzed by three isotherm models (Langmuir, Freundlich and Dubinin-Radushkevich), and three kinetic models including the pseudo-first-order, the pseudo-second-order and intraparticle diffusion equations using nonlinear regression technique. Langmuir isotherm was the best to fit the experimental data (R-2 = 0.971). The maximum adsorption capacity was 0.158 mol kg(-1) from Langmuir isotherm model. Maximum removal efficiency was found approximately 66% for the initial Pb(II) concentration of 1000 mg/L, adsorbent dosage of 100 mg and agitation speed of 150 rpm at pH 4.5. The adsorption free energy was found as E-DR (15.8 kJ mol(-1)), which indicated that Pb(II) adsorption process onto Ch-S composite was chemically performed. The kinetic studies have shown that the best fitted kinetic model is the pseudo-first order (R-2 = 0.979). Adsorption enthalpy value was determined as 18.7 kJ mol(-1), adsorption entropy was found as 106 J mol(-1) K-1, and Gibbs free energy was found as 12.9 kJ mol(-1). The thermodynamic parameters showed that the adsorption of Pb(II) on Ch-S was endothermic, possible and spontaneous.Article Citation - WoS: 6Citation - Scopus: 6Experimental and Statistical Damage Analysis in Milling of S2-Glass Fiber/Epoxy and Basalt Fiber/Epoxy Composites(Wiley, 2024-07-30) Sayin, Ahmed Cagri; Danisman, Sengul; Ersoy, Emin; Yilmaz, Cagatay; Kesriklioglu, SinanS2-glass fiber reinforced plastics (S2-GFRP) and basalt fiber reinforced plastics (BFRP) have emerged as crucial materials due to their exceptional mechanical properties, and milling of composite materials plays an important role in achieving desired properties. However, they have proven challenges due to relative inhomogeneity compared with metals, resulting unpredictability in quality of milling operations. The objective of this work is to investigate the effect of cutting parameters, tool geometry and tool surface materials on the surface quality of composites using burrs as a metric. S2-GFRP and BFRP composites were produced by the vacuum infusion method. Helical and straight flute end mills were manufactured from high-speed steel (HSS) and carbide rounds, and half of them were coated with titanium nitride using reactive magnetron sputtering technique. Taguchi L18 orthogonal array is used to determine the effect of tool material, tool angle, coating, cutting direction, spindle speed, and feed rate on the machining quality of S2-GFRPs and BFRPs with respect to burr formations. Milling experiments were conducted under dry conditions and then the burrs were imaged to calculate the total area and length. Statistical analysis was also performed to optimize the machining parameters and tool type for ensuring the structural integrity and performance of the final composite parts. The results showed that the selection of tool material has the most significant impact on the burr area and length of the machined surface. The novel image analysis allows to analyze the extent of the burr size with a desirable operation speed for industrial applications.