Scopus İndeksli Yayınlar Koleksiyonu
Permanent URI for this collectionhttps://hdl.handle.net/20.500.12573/395
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Article Comprehensive Evaluation of Microstructure–Property Relationships in Al-Added Sn-Zn Eutectic Solder Alloys from Thermal, Electrical, and Mechanical Perspectives(Springer, 2026) Bayram, Ümit; Şahin, Mevlüt(Sn-8.8Zn)-XAl (X = 0, 0.5, 1.0, 2.5, 5.0 wt.%) solder alloys were produced using a vacuum muffle furnace. The microstructural images, chemical compositions, and phase structures of the alloys were characterized by field emission scanning electron microscopy (FESEM), field emission scanning electron microscopy-energy dispersive x-ray spectroscopy (FESEM-EDX), and x-ray diffraction (XRD) analyses, respectively. According to FESEM images, a fully eutectic microstructure was observed in the Sn-8.8Zn alloy. With increasing Al content, dendritic structures formed and became denser. The mechanical properties of the alloys (ultimate tensile strength sigma UT, tensile yield strength sigma TY, compressive yield strength sigma CY, and Vickers hardness HV) were measured as a function of composition. The highest strength and hardness values were obtained for the (Sn-8.8Zn)-2.5Al alloy, whereas the (Sn-8.8Zn)-5.0Al alloy exhibited the highest ductility. The melting enthalpies (Delta H) and the specific heat differences between the solid and liquid phases (Delta CP) of the alloys were measured by differential scanning calorimetry (DSC) analysis. It was determined that an increase in the Al content of the eutectic alloy resulted in higher measured thermophysical properties. Finally, electrical resistivity (rho) values at T = 300 K, measured using the standard four-point probe method (FPPM), revealed an increase in resistivity up to 1.0 wt.% Al content, followed by a decrease beyond this value. In contrast, thermal conductivity values calculated using the Wiedemann-Franz law exhibited an opposite trend, decreasing up to 1.0 wt.% Al, and increasing thereafter. Based on microstructure-property relationships, the results were compared with previous studies, highlighting that (Sn-8.8Zn)-XAl alloys represent promising alternatives to lead-free solders.Article Densification-Induced Chemical Reorganization and Mechanical Enhancement in Amorphous Si2BC3N(Elsevier, 2026-02) Durandurdu, MuratThe atomistic mechanisms that govern the mechanical performance of amorphous silicon-boron carbonitride (SiBCN) ceramics remain insufficiently understood, particularly regarding the role of density. Here, we employ ab initio molecular dynamics simulations to elucidate the structural evolution and mechanical response of low-density (LDA, 2.20 g/cm3) and high-density (HDA, 2.53 g/cm3) amorphous Si2BC3N prepared via melt-quench. The HDA phase exhibits markedly higher atomic packing and network connectivity, accompanied by a nontrivial chemical reorganization. Densification significantly enhances heteronuclear bonding-especially Si-C coordination-while suppressing C-C and Si-Si homopolar bonds. These changes yield substantial mechanical strengthening: the HDA phase exhibits a 48% increase in bulk modulus (130 GPa vs. 88 GPa), along with elevated Young's (266 GPa) and shear (112 GPa) moduli. Our findings reveal a clear density-structure-property relationship in amorphous SiBCN, demonstrating that densification suppresses weak self-bonded motifs and promotes a robust, interconnected atomic network. This insight provides a pathway for designing high-performance amorphous SiBCN ceramics for extreme-environment applications.Article Effects of Strain Rate and Post Processing on Mechanical Properties of Additively Manufactured AlSi10Mg Alloys(Walter de Gruyter GmbH, 2026-01-12) Karaveli, K.K.; Bal, B.The mechanical properties of AlSi10Mg alloy fabricated by laser powder bed fusion (LPBF) were investigated under different strain rates and post-processing conditions, including shot peening (SP) and stress relief (SR). Tensile tests were performed at quasistatic (0.1 s−1) and dynamic (0.015 s−1) strain rates on as-built and post-processed specimens. The results revealed that SP significantly increased the yield strength by 7.10 %, reaching 249.59 MPa, due to the induced compressive residual stresses. However, while SP slightly improved the ultimate tensile strength (UTS) by 0.25 %, it also reduced elongation at break by 18.06 %, indicating a trade-off between strength and ductility. Conversely, SR improved ductility by reducing internal stresses, leading to an elongation at break increase of 574.01 %, with a slight reduction in yield strength. The combination of SP and SR exhibited a synergistic effect, achieving a balance between strength and ductility. Strain rate sensitivity (SRS) analysis indicated that stress-relieved specimens performed better under dynamic loading conditions. These findings highlight the potential of post-processing techniques in tailoring the mechanical behavior of LPBF-produced AlSi10Mg alloys. The balanced properties achieved through combined treatments make this material particularly suitable for high-performance aerospace and automotive applications, where strength and ductility are critical under varying operational conditions. © 2025 Walter de Gruyter GmbH, Berlin/Boston.Article Citation - WoS: 10Citation - Scopus: 12The Effect of Ultrasonic Cleaning Upon Mechanical Properties of Metal Matrix Composites(Springer india, 2020-11-20) Aslan, Abdullah; Salur, Emin; Gunes, Aydin; Sahin, Omer Sinan; Karadag, Hakan Burak; Akdemir, AhmetThe aim of this study is to produce composite materials by recycling metallic chips, which are found in industry as a large amount of waste. In addition, it is aimed to investigate the effect of ultrasonic cleaning process as the consolidation behavior and mechanical properties of bulk material directly depend on the cleaning of waste metallic chips. In the present investigation, spheroidal graphite cast iron (GGG-40) was employed as reinforcement material in tin bronze (CuSn10) matrix system. GGG-40 and CuSn10 chips were cleaned by ultrasonic agitation in water for 20 and 40 min. Consolidation of the cleaned metallic chips was achieved with a hot press by applying 820 MPa pressure under 450 degrees C, and the cylindrical and prismatic metal matrix composite materials with different reinforcement ratios were successfully produced. Energy-dispersive X-ray and scanning electron microscopy analyses were carried out to determine the amount of the oxide removed from the surfaces of chips. The mechanical properties of the samples were determined by hardness, porosity, compression and three-point bending tests. According to the results of the analyses, it was found that CuSn10 surfaces were cleaned from 20%, 50% and GGG-40 surfaces from 35%, 39% oxides during 20- and 40-min cleaning time, respectively. In addition, the results of the mechanical tests revealed that increased ultrasonic cleaning time improves the consolidation quality of metallic chips and it provides successful covering of GGG-40 chips by the CuSn10 chips as a result of a better structural integrity. New machinery parts with high mechanical properties can be produced as a result of recycling of the metallic chips which are available as waste in industry by appropriate cleaning process and this situation makes this study more innovative, economical and environmentally friendly research.Article Citation - WoS: 4Citation - Scopus: 2Development of High-Performance Nanostructured Aluminum and Its Constitutive Modeling(Taylor & Francis inc, 2023-10-11) Deka, Surja; Mozafari, Farzin; Mallick, Ashis; Thamburaja, Prakash; Gupta, ManojA new technique, an in-situ hot-extrusion-based synthesizing process, is proposed to develop high-performance nanocrystalline aluminum (nc-Al) with an optimally tuned strength-to-ductility ratio suitable for various technologically relevant applications. Comprehensive investigations are conducted by characterizing mechanical and microstructural properties to realize the influence of various synthesizing variables on the properties of the bulk nc-Al. Furthermore, a continuum-scale constitutive modeling approach is proposed based on dominant microstructural mechanisms of plastic deformation and implemented into a finite element solver using a user-defined material interface. It is shown that the proposed theory can provide a versatile platform to predict the nanocrystalline aluminum mechanical response quite well.Article Citation - WoS: 4Citation - Scopus: 5An In-Depth Investigation of Mg-Zn Metallic Glasses: A First Principles Study(Elsevier, 2018-10) Erkartal, Mustafa; Durandurdu, MuratThe atomic structures, glass forming evolutions, mechanical properties and high pressure behavior of Mg75Zn20Ca5 and Mg60Zn35Ca5 bulk metallic glasses, which are promising candidates for biomedical implants, have been examined by using ab initio molecular dynamics simulations. The pair-distribution function and coordination number analyses show that increasing Zn content in the alloy results in a decrease in several bond distances and an increase in the total coordination number of each species due to the atomic size difference between Mg and Zn atoms. According to the Voronoi tessellation, bond pair and bond angle distribution analyzes, the fivefold geometrical arrangements (pentagonal-bipyramid) are the most predominant in the first coordination shell, indicating the stability of the amorphous states and their dense atomic packing. The most striking result emerged from the calculations of mechanical properties is that an increase of Zn (>= 30%) content in the alloy yields embrittlement in the alloys. Under uniaxial compressions, both compositions undergo structural failure between 6 and 8 GPa. Under hydrostatic pressure, a diminishing in fcc/hcp ordering and an enlargement of the ideal icosahedral ordering may indicate a more disordered structure. In our view, these results represent a good step toward understanding the atomic structures Mg-Zn-Ca bulk metallic glasses.Article Citation - WoS: 2Citation - Scopus: 2Amorphous Silicon Triboride: A First Principles Study(Elsevier, 2020-05) Ozlem, Aysegul; Karacaoglan, Cetin; Durandurdu, Murat; Çetin Karacaoğlan, Ayşegül ÖzlemUsing ab initio molecular dynamics simulations, an amorphous silicon triboride (a-SiB3) network is generated and its atomic structure, electronic features and mechanical properties are compared with those of the crystal. The average coordination number of B and Si atoms in a-SiB3 is found as 5.8 and 4.6, correspondingly, close to 6.0 (B atom) and 5.0 (Si atom) in the crystal. A careful investigation reveals partial structural similarities around B atoms but not around Si atoms in both phases of SiB3. The presence of B-12, B11Si and B-10 molecules is witnessed in a-SiB3. The last two molecules, however, do not exist in the crystal. a-SiB3 is a semiconducting material. The bulk modulus of the ordered and disordered structures is projected to be 151 GPa and 131 GPa, respectively. The Vickers hardness of a-SiB3 is calculated to be similar to 13-15 GPa, less than similar to 20-25 GPa estimated for the crystal.Article Citation - WoS: 3Citation - Scopus: 3Ab Initio Study of Boron-Rich Amorphous Boron Carbides(Wiley, 2023-01-10) Yildiz, Tevhide Ayca; Durandurdu, MuratAmorphous boron carbide compositions having high B contents (BxC1-x, 0.50 <= x <= 0.95) are systematically created by way of ab initio molecular dynamics calculations, and their structural, electrical, and mechanical characteristics are inclusively investigated. The coordination number of both B and C atoms increases progressively with increasing B/C ratio and more close-packed materials having pentagonal pyramid motifs form. An amorphous diamond-like local arrangement is found to be dominant up to 65% B content, and beyond this content, a mixed state of amorphous diamond- and B-like structures is perceived in the models because sp(3) hybridization around C atoms is still leading one for all compositions. The pentagonal pyramid motifs around C atoms are anticipated to appear beyond 65% content. The intericosahedral linear C-B-C chains do not form in any model. All amorphous boron carbides are semiconducting materials. The mechanical properties gradually increase with increasing B concentration, and some amorphous compositions are proposed to be hard materials on the basis of their Vickers hardness estimation.