Scopus İndeksli Yayınlar Koleksiyonu
Permanent URI for this collectionhttps://hdl.handle.net/20.500.12573/395
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Article Effects of Alkanolamines on Calcium Sulfoaluminate Belite Cement Hydration and Fresh Properties(Emerald Group Publishing Ltd, 2026) Uzal, Burak; Wilkinson, Angus P.; Qoku, Elsa; Nguyen, Tu-Nam; Kurtis, Kimberly E.Calcium sulfoaluminate belite cements have found widespread use in specialised applications but have not been applied broadly due to rapid setting times. Conventional set retarders such as citric and tartaric acids modify hydration kinetics, introducing ancillary effects that alkanolamines may avoid. This study examined the effects of three alkanolamines, triisopropanolamine (), triethanolamine () and diisopropanolamine (), on early hydration at 0.02% dosage; was also tested across a broader dosage range. Reaction kinetics and phase evolution were examined in pastes by calorimetry, thermogravimetric analysis () and in situ quantitative X-ray diffraction () for 72 h of hydration, along with setting time and amplitude-sweep rheometry. Calorimetry showed that and delayed and reduced the main cement hydration peak, while all alkanolamines delayed and enhanced the shoulder and secondary hydration peaks. In situ and suggested that alkanolamines decrease ettringite and alumina gel formation by 24 h and may lead to poorly crystallised ettringite that cannot be quantified by . Alkanolamine-containing samples demonstrated increased storage and loss moduli and extended linear viscoelastic ranges. A consistent grouping of similar behaviour emerged: control/TIPA versus TEA/DIPA, suggesting distinct mechanisms. Finally, among the alkanolamines, was the most effective, increasing the setting time by 18 min.Article Citation - WoS: 5Citation - Scopus: 6Solution of Jamming Transition Problem Using Adomian Decomposition Method(Emerald Group Publishing Ltd, 2018-08-08) Senturk, Erman; Coskun, Safa Bozkurt; Atay, Mehmet TarikPurpose The purpose of the study is to obtain an analytical approximate solution for jamming transition problem (JTP) using Adomian decomposition method (ADM). Design/methodology/approach In this study, the jamming transition is presented as a result of spontaneous deviations of headway and velocity that is caused by the acceleration/breaking rate to be higher than the critical value. Dissipative dynamics of traffic flow can be represented within the framework of the Lorenz scheme based on the car-following model in the one-lane highway. Through this paper, an analytical approximation for the solution is calculated via ADM that leads to a solution for headway deviation as a function of time. Findings A highly nonlinear differential equation having no exact solution due to JTP is considered and headway deviation is obtained implementing a number of different initial conditions. The results are discussed and compared with the available data in the literature and numerical solutions obtained from a built-in numerical function of the mathematical software used in the study. The advantage of using ADM for the problem is presented in the study and discussed on the basis of the results produced by the applied method. Originality/value This is the first study to apply ADM to JTP.