Scopus İndeksli Yayınlar Koleksiyonu
Permanent URI for this collectionhttps://hdl.handle.net/20.500.12573/395
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Article Citation - WoS: 19Citation - Scopus: 21Effect of Characteristics of Natural Zeolites on Their Geopolymerization(Elsevier, 2021-12) Ozen, Sevgi; Uzal, BurakThe properties of clinoptilolite-based geopolymers are investigated with a focus on the parameters affecting the reactivity of clinoptilolite in a geopolymer binder. A complete characterization of raw materials was carried out as well as a determination of the mineralogical composition, microstructure and mechanical properties of geopolymers. The results of the investigation show that of the investigated materials, geopolymer made with clinoptilolite-bearing tuff from Bayburt has the highest compressive strength. The chemical and mineralogical characteristics of a raw material are important parameters that potentially control the geopolymeric reaction, whereas physical properties (particle size and BET specific surface area) are mainly influential at early stages of geopolymerization. Geopolymeric gel was found to be the main reaction product through characterization by XRD and SEM analysis. The geopolymer produced with the raw material from Bayburt had a narrow range of Si/Al ratios and possessed a geopolymer binder structure with an advanced nature. Lastly, in addition to clinoptilolite, feldspar has an additional effect on the geopolymeric reaction and enhances the process, especially at later ages.Article Citation - WoS: 32Citation - Scopus: 35A New Parameter Influencing the Reaction Kinetics and Properties of Fly Ash Based Geopolymers: A Pre-Rest Period Before Heat Curing(Elsevier, 2021-03) Durak, Ugur; Ilkentapar, Serhan; Karahan, Okan; Uzal, Burak; Atis, Cengiz DuranIn this study, the influence of a pre-rest period before heat curing (as a new parameter), on the physical properties, flexural and compressive strength, and microstructure of geopolymer mortars and pastes produced with alkali activation of fly ash were investigated. In this context, geopolymer mortar and paste samples were prepared and pre-rested under laboratory conditions for 0, 1, 2, 3, 7, 14, and 28 days before heat curing. After the pre-rest period, the samples were subjected to heat curing at 75 degrees C in an oven, for 2 days. Mortar and paste samples exposed to a pre-rest period while in the fresh state before heat curing were compared with control samples without pre-resting. Water absorption, porosity, specific gravity, capillarity, flexural strength, compressive strength, and abrasion resistance tests were conducted on the geopolymer mortar samples. A reaction kinetics study using an isothermal calorimeter, XRD, and SEM analyses were performed on the geopolymer paste samples for microstructural investigations. Based on the results obtained, it was observed that the mechanical strength of the samples subjected to the pre-rest period before heat curing increased considerably compared to the reference (without pre-resting) samples. In addition, because of pre-resting, the capillarity coefficient, water permeability, and porosity of the samples decreased compared to the reference samples, and it was concluded that pre-resting improves durability-related properties. Moreover, the reaction kinetics and SEM analysis results, supporting the above findings, showed that a pre-resting period increases the geopolymeric reaction products and causes a denser microstructure.Article Citation - WoS: 53Citation - Scopus: 55Comprehensive Experimental Analysis of the Effects of Elevated Temperatures in Geopolymer Concretes With Variable Alkali Activator Ratios(Elsevier, 2023) Ozbayrak, Ahmet; Kucukgoncu, Hurmet; Aslanbay, Huseyin Hilmi; Aslanbay, Yuksel Gul; Atas, OguzhanBy growing population and rapid urbanization, demand for concrete increases exponentially. Researches on use of fly ash material in waste product class for concrete production are important to produce concrete more environmentally friendly. However, there is a need for more research to use geopolymer concrete (GPC) in every field where ordinary Portland cement concrete (OPC) is used. Therefore, it is crucial to experimentally investigate thermal properties as well as me-chanical properties of geopolymer concrete. As investigated thermal properties, the main factor affecting strength development of GPC is alkali activator ratios. In this study, GPC prism samples with nine different compositions, produced by various alkali ratios. After flexural strength tests, they were cut into cubes and exposed to 400 degrees C, 600 degrees C and 800 degrees C, then they were subjected to compressive strength tests. Results obtained from different AA/FA and SS/SH ratios were eval-uated as mechanical properties at ambient temperature and physical, mechanical and micro-structural properties at elevated temperature. An empirical formula, which considers the effect of activator ratios, was proposed to calculate flexural strength depending on compressive strength of samples at ambient temperature. As an increase of SS/SH and AA/FA ratios, compressive strength increased, while flexural strength decreased. The increase in AA/FA ratio decreased compressive strength of samples exposed to high temperatures, while increase in SS/SH ratio did not deter-mine at elevated temperatures. There is an inverse change with AA/FA ratio and parallel change with SS/SH ratio between compressive strengths of samples at ambient temperature and exposed to high temperature.