Scopus İndeksli Yayınlar Koleksiyonu
Permanent URI for this collectionhttps://hdl.handle.net/20.500.12573/395
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Article Citation - WoS: 1Citation - Scopus: 1A Novel Bifunctional Organic Supported Nano-Titania Photocatalyst via the Sol-Gel Method Using Walnut-Shell(Elsevier, 2026-01) Erdem, IlkerNano-structured photocatalytic titania was prepared via the sol-gel method on the surface of carbon-rich organic support in situ to be used as a supported photocatalyst. The preparation process was lean, including sol preparation, mixing and calcination (450 degrees C). The microstructure and crystallinity were characterized by using SEM and XRD analysis. The prepared photocatalytic material shows better water clarification (dye removal) efficiencies than commercial nano titania, either excited by UV or visible light, or kept in the darkness. A bifunctional composite having both photocatalysis and adsorption capabilities simultaneously was prepared using walnut shell (WNS) as organic support for the first time. It has considerably higher dye removal rates (kapp values (min(-1))) when compared with commercial nano titania: 0.1827 (2.83 times higher), 0.1188 (9.35 times higher) and 0.1066 (12.25 times higher) under UV light, under visible light, and in the darkness, respectively, making it a promising candidate for water clarification processes.Article Gazlaştırma Tesisi Odun Atığı ve Sivas Kangal Linyit Kömürünün Boya Adsorpsiyonunda Kullanım Olanaklarının Araştırılması(Chamber of Mining Engineers of Turkey, 2020-12-01) Kırma, Ramazan; Sarikaya, Musa; Top, S.; Uçkun, Şükrü; Timür, İrfanIn this study, the usage possibilities of wood waste obtained from Gebze MDF and Particle Board Gasification Plant preliminary studies and Sivas Kangal lignite coal as absorbents were investigated. In this way, it was aimed both to evaluate the wastes and to prevent environmental pollution with materials that are cheaper and easier to obtain. The structure and surface properties of wood waste and coal samples crushed and ground to -75 µm size and used as adsorbent were investigated by XRD, SEM and BET analyses. In addition, samples have been characterized by elemental, ash, moisture, volatile matter and fixed carbon analyses. In the experiments, methylene blue (MM) with the formulation of C<inf>16</inf>H<inf>18</inf>CIN<inf>3</inf>S.xH<inf>2</inf>O was used. The effects of temperature, mixing time and concentration parameters on MM adsorption were investigated. Langmuir isotherms were created for different temperatures at optimum concentrations. As a result, it has been revealed that lignite coal and wood waste can be used as adsorbent. A 10 ppm MM for lignite coal and 3 ppm MM for wood waste were determined to be ideal concentrations for adsorption. © 2022 Elsevier B.V., All rights reserved.