Mühendislik Fakültesi
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Article A rational utilization of reinforcement material for flexural design of 3D-printed composite beams(SAGE PUBLICATIONS LTD, 1 OLIVERS YARD, 55 CITY ROAD, LONDON EC1Y 1SP, ENGLAND, 2019) Ciftci, Cihan; Sas, Hatice S.Recent developments in composite industry address the adaptation of 3D printing technology to overcome the design and manufacturing challenges of the traditional composite processing techniques. This adaptation can be performed with the development of design methodologies corresponding to the type of structural load-carrying members in a structure. Considering the frequently use of beams in structures, the development of the design methodology of beams is essential for the adaptation of the additive manufacturing. Therefore, in this paper, the flexural loading concept is analytically formulated to derive moment capacity for the flexural behavior of 3D-printed composite beams. Then, the formulation is adapted to develop a design methodology of 3D-printed laminates under flexural loading. Additionally, the analytical solutions developed for the design methodology presented in this paper were verified with a good agreement with experimental studies.Article Citation - WoS: 23Citation - Scopus: 23Pressure-Induced Amorphization of MOF-5: A First Principles Study(Wiley-VCH Verlag GmbH, 2018) Erkartal, Mustafa; Durandurdu, Murat; Erkartal, Mustafa; Durandurdu, MuratAmorphous metal-organic frameworks (MOFs) and the amorphization of crystalline MOFs under mechanical stimuli are attracting considerable interest in last few years. However, we still have limited knowledge on their atomic arrangement and the physical origin of crystalline-to-amorphous phase transitions under mechanical stimuli. In this study, ab initio simulations within a generalized gradient approximation are carried out to investigate the high-pressure behavior of MOF-5. Similar to the previous experimental findings, a pressure-induced amorphization is observed at 2 GPa through the simulations. The phase transformation is an irreversible first order transition and accompanied by around 68% volume collapse. Remarkably, the transition arises from local distortions and, contrary to previous suggestions, does not involve any bond breaking and formation. Additionally, a drastic band gap closure is perceived for the amorphous state. This study has gone some way towards enhancing our understanding of pressure-induced amorphization in MOFs.Article Human identification using palm print images based on deep learning methods and gray wolf optimization algorithm(SPRINGER, 2024) Alshakree, Firas; Akbas, Ayhan; Rahebi, JavadPalm print identification is a biometric technique that relies on the distinctive characteristics of a person’s palm print to distinguish and authenticate their identity. The unique pattern of ridges, lines, and other features present on the palm allows for the identification of an individual. The ridges and lines on the palm are formed during embryonic development and remain relatively unchanged throughout a person’s lifetime, making palm prints an ideal candidate for biometric identification. Using deep learning networks, such as GoogLeNet, SqueezeNet, and AlexNet combined with gray wolf optimization, we achieved to extract and analyze the unique features of a person’s palm print to create a digital representation that can be used for identification purposes with a high degree of accuracy. To this end, two well-known datasets, the Hong Kong Polytechnic University dataset and the Tongji Contactless dataset, were used for testing and evaluation. The recognition rate of the proposed method was compared with other existing methods such as principal component analysis, including local binary pattern and Laplacian of Gaussian-Gabor transform. The results demonstrate that the proposed method outperforms other methods with a recognition rate of 96.72%. These findings show that the combination of deep learning and gray wolf optimization can effectively improve the accuracy of human identification using palm print images.Article Citation - WoS: 6Citation - Scopus: 7Synergistic Effect of Organic Acid on the Dissolution of Mixed Nickel-Cobalt Hydroxide Precipitate in Sulphuric Acid Solution(Edp Sciences S A, 2019) Kursunoglu, Sait; Kursunoglu, SaitThe synergistic effect of an organic acid on the dissolution of nickel and cobalt from a mixed nickel-cobalt hydroxide precipitate (MHP) in sulphuric acid solution was studied. The effects of sulphuric acid concentration, the type of organic acid, leaching time, leaching temperature and stirring speed on the dissolution of the metals were experimentally investigated. It was observed that there is no beneficial effect of leaching temperature and stirring speed on the dissolution of the metals from the used MHP product which contains 37.7% Ni, 2.1% Co and 5.6% Mn. It was found that citric acid was more effective than oxalic acid for the dissolution of nickel and manganese, whereas oxalic acid was more effective than citric acid for the dissolution of cobalt. The addition of oxalic acid into the leaching system, however, affected the dissolution of nickel negatively because nickel precipitate as nickel oxalate. Therefore, the use of citric acid as synergist for sulphuric acid leaching of MHP product is more promising. After 60 min of leaching, 90.9% Ni, 84.2% Co and 98.1% Mn were dissolved under the following conditions: 0.75 M sulphuric acid, 2 g citric acid, 1/10 solid-to-liquid ratio, 400 rpm stirring speed and 30 degrees C temperature. The experimental results demonstrate that the addition of citric acid as a synergist for sulphuric acid leaching of a MHP product provides beneficial effect for the dissolution of nickel, cobalt and manganese.Article Citation - WoS: 43Citation - Scopus: 45Highly Efficient Cd-Free Alloyed Core/Shell Quantum Dots With Optimized Precursor Concentrations(Amer Chemical Soc, 2016) Altintas, Yemliha; Talpur, Mohammad Younis; Unlu, Miray; Mutlugun, EvrenThe chemical composition, the emission spectral bandwidth, and photoluminescence quantum yield of a semiconductor quantum dot (QD) play an important role in the assessment of the performance of the applications related to the quantum dots. Quantum dots based on environmentally friendly compositions with high optical performance have been in demand for high-end technological applications. In this work, we propose and demonstrate a detailed synthesis approach for environmentally friendly and highly efficient InPZnS alloy/ZnS shell quantum dots. Following a systematic study of the ratio and type of the precursors involved, we achieved alloyed core shell InPZnS/ZnS QDs with tunable emission across the visible spectrum, having a record quantum efficiency up to 78% along with a full width at half-maximum as narrow as 45 nm. The effect of the systematic shell growth has been further investigated using time-resolved photoluminescence characterizations along with the observation of the suppression of the nonradiative decay channels, with the photoluminescence lifetime prolonged from 20.3 to 50.4 ns. The development of highly efficient and environmentally friendly QDs will pave the way for robust, sustainable optoelectronic applications.