WoS İndeksli Yayınlar Koleksiyonu
Permanent URI for this collectionhttps://hdl.handle.net/20.500.12573/394
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Article Citation - WoS: 9Citation - Scopus: 9Reaction Kinetics and Properties of Pumice-Based Geopolymer Systems Cured at Room Temperature(Elsevier Sci Ltd, 2023-12) Kucukyildirim, Enver; Yorulmaz, Hediye; Durak, Ugur; Ilkentapar, Serhan; Uzal, Burak; Karahan, Okan; Atis, Cengiz DuranThis research investigated the kinetics of pumice-based geopolymer systems and their physical and mechanical properties. The effect of the Na2SiO3/NaOH ratio of geopolymer systems on the rate of heat evolution and total heat of reaction were examined via isothermal calorimetry of geopolymer pastes prepared with Na2SiO3/NaOH ratios of 2.5, 3, and 3.5. Hardened pastes were also studied with thermo-gravimetric analysis to determine weight loss. In addition, the unit weights and compressive strengths of the pastes prepared using pumice were measured. Although the hydration process starts the earliest in pumice-based geopolymer pastes with a Na2SiO3/ NaOH ratio of 2, they have the lowest total hydration temperature. Na2SiO3/NaOH ratio of 2.5 by mass, shows higher weight loss obtained from TGA results. The compressive strength of the paste sample, prepared with a Na2SiO3/NaOH ratio of 3.5 by mass, was the highest, with 36.30 MPa at 28d. Depending on the Na2SiO3/NaOH ratio, it is thought that as the amount of Na2SiO3 increases in the samples, silica gel formation increases in later ages.Article Citation - WoS: 80Citation - Scopus: 90Properties of Fly Ash-Based Lightweight Geopolymer Concrete Prepared Using Pumice and Expanded Perlite as Aggregates(Elsevier, 2020-02) Top, Soner; Vapur, Huseyin; Altiner, Mahmut; Kaya, Dogan; Ekicibil, AhmetThe present paper aims to utilize the fly ash wastes with lightweight aggregates for geopolymer concrete production process in which sodium hydroxide (NaOH) and sodium metasilicate (Na2SiO3) were used as alkali activators, respectively. The designed experiments were examined by the Yates Analyses and so the productions of geopolymer concrete were investigated depending on curing temperature, solid/liquid rate and concentration of alkali activators. The curing temperature and alkali activator concentration were revealed as effective parameters in geopolymerization. The effects of expanded perlite (EP) and acidic pumice (AP) aggregates were discovered for the production of lightweight geopolymer concretes. The microstructural properties of each produced geopolymer concrete were characterized using SEM, EDS and laser particle size analyses. The specifications of the concrete were evaluated based on their uniaxial compressive strength (UCS), point load strength (PLS), sonic speed (SS), Mohs hardness (MH), and water absorption (WAR) ratio results. In addition, the effects of pre-wetting of EP aggregates, which have hydrophilic nature, were examined. To the best of our knowledge, this is the first time that pre-wetted lightweight EP aggregates were used to produce lightweight GP concretes. As a result of pre-wetting, chemical usage decreased by 32.5%. The UCSs of the lightweight geopolymer concretes were in a range of 10-50MPa and their unit weights changed between 1250 and 1700 kg/m(3). Lighter concretes were obtained by the addition of EP aggregates rather than AP ones. (C) 2019 Elsevier B.V. All rights reserved.Article Citation - WoS: 8Citation - Scopus: 9A New Quantitative Welding Degree Classification for Ignimbrites(Springer, 2023-06-28) Akin, Mutluhan; Topal, Tamer; Dincer, Ismail; Akin, Muge K.; Ozvan, Ali; Orhan, Ahmet; Orhan, AyseAs a pyroclastic rock type, ignimbrites may reveal varying degrees of welding depending on the temperature (> 535 celcius) and overburden pressure conditions during its formation. The welding degree of ignimbrites increases as the formation temperature and the thickness of the overburden deposit in the depositional environment escalate, which are the most crucial factors controlling the rate of welding in ignimbrites. With the increasing temperature, plastic deformation is observed in ignimbrites and the glassy minerals are being welded. Furthermore, the thickness of the overburden causes the deformation of the ash matrix in ignimbrites at the lower sections and the pumice grains are flattened at different rates. An increase in the degree of welding of ignimbrites causes an improvement in the physical and mechanical properties of the rock material as well. Within the scope of this research, petrographical, mineralogical, and geochemical studies were carried out on a total of 16 different ignimbrite types, which have different color and texture properties, obtained from three different regions of Turkey (Kayseri, Nevsehir, Ahlat) where ignimbrites extensively crop out, and the physical and mechanical properties of these samples were revealed. Consequently, a new welding classification was developed for ignimbrites considering the uniaxial compressive strength and dry unit weight. The proposed welding classification consists of six classes ranging from non-welded to highly welded. When the welding degrees of the selected ignimbrites are evaluated, Kayseri ignimbrites mostly exhibit moderate welding characteristics. Nevsehir ignimbrites, on the other hand, have a low welding degree whereas the degree of welding in Ahlat ignimbrites may vary from low to high. Additionally, long and short axis lengths of pumice grains in the ignimbrite specimens were determined by measuring under the microscope, and shape ratios were determined by different shape parameter evaluation methods. As a result, it has been concluded that the pumice grains in Kayseri and Ahlat ignimbrites have a more lenticular structure than the pumice grains in Nevsehir ignimbrites. Eventually, the welding degree classes of ignimbrites and the classification developed by using threshold values of the oblateness ratio (OR) values of pumice grains at different welding degrees are quite compatible. The proposed welding degree classification is of great importance in the selection of ignimbrites widely used as dimension stone and in terms of engineering classification of this rock type as well as it will guide to the scientific studies to be performed on ignimbrites with varying physical and mechanical properties.