WoS İndeksli Yayınlar Koleksiyonu
Permanent URI for this collectionhttps://hdl.handle.net/20.500.12573/394
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Article Densification-Induced Chemical Reorganization and Mechanical Enhancement in Amorphous Si2BC3N(Elsevier, 2026-02) Durandurdu, MuratThe atomistic mechanisms that govern the mechanical performance of amorphous silicon-boron carbonitride (SiBCN) ceramics remain insufficiently understood, particularly regarding the role of density. Here, we employ ab initio molecular dynamics simulations to elucidate the structural evolution and mechanical response of low-density (LDA, 2.20 g/cm3) and high-density (HDA, 2.53 g/cm3) amorphous Si2BC3N prepared via melt-quench. The HDA phase exhibits markedly higher atomic packing and network connectivity, accompanied by a nontrivial chemical reorganization. Densification significantly enhances heteronuclear bonding-especially Si-C coordination-while suppressing C-C and Si-Si homopolar bonds. These changes yield substantial mechanical strengthening: the HDA phase exhibits a 48% increase in bulk modulus (130 GPa vs. 88 GPa), along with elevated Young's (266 GPa) and shear (112 GPa) moduli. Our findings reveal a clear density-structure-property relationship in amorphous SiBCN, demonstrating that densification suppresses weak self-bonded motifs and promotes a robust, interconnected atomic network. This insight provides a pathway for designing high-performance amorphous SiBCN ceramics for extreme-environment applications.Article Effects of Strain Rate and Post Processing on Mechanical Properties of Additively Manufactured AlSi10Mg Alloys(Walter de Gruyter GmbH, 2026-01-12) Karaveli, K.K.; Bal, B.The mechanical properties of AlSi10Mg alloy fabricated by laser powder bed fusion (LPBF) were investigated under different strain rates and post-processing conditions, including shot peening (SP) and stress relief (SR). Tensile tests were performed at quasistatic (0.1 s−1) and dynamic (0.015 s−1) strain rates on as-built and post-processed specimens. The results revealed that SP significantly increased the yield strength by 7.10 %, reaching 249.59 MPa, due to the induced compressive residual stresses. However, while SP slightly improved the ultimate tensile strength (UTS) by 0.25 %, it also reduced elongation at break by 18.06 %, indicating a trade-off between strength and ductility. Conversely, SR improved ductility by reducing internal stresses, leading to an elongation at break increase of 574.01 %, with a slight reduction in yield strength. The combination of SP and SR exhibited a synergistic effect, achieving a balance between strength and ductility. Strain rate sensitivity (SRS) analysis indicated that stress-relieved specimens performed better under dynamic loading conditions. These findings highlight the potential of post-processing techniques in tailoring the mechanical behavior of LPBF-produced AlSi10Mg alloys. The balanced properties achieved through combined treatments make this material particularly suitable for high-performance aerospace and automotive applications, where strength and ductility are critical under varying operational conditions. © 2025 Walter de Gruyter GmbH, Berlin/Boston.Article Tuning Mechanical Performance of PCL Scaffolds: Influence of 3D Bioprinting Parameters, Polymer Concentration, and Solvent Selection(IOP Publishing Ltd, 2025-09-01) Ceylan, Saniye Aylin; Baltacioglu, Mehmet Furkan; Bal, Burak; Bayram, Ferdi Caner; Isoglu, Ismail AlperThe mechanical performance of three-dimensional (3D) bioprinted scaffolds is susceptible to printing parameters and material formulation. In this study, poly (epsilon-caprolactone) (PCL) scaffolds were fabricated using four different polymer concentrations (10%, 25%, 50%, and 75% w/v) to investigate how these variations, along with process parameters, influence mechanical behavior. Maintaining the structural integrity of bioprinted constructs requires careful optimization of polymer concentration and precise control over parameters such as printing speed, pressure, and infill density. Tensile tests were conducted to evaluate the effects of these variables. Among the tested conditions, a 50% (w/v) concentration allowed for a broader operational window, enabling fabrication across a range of printing speeds and pressures. At a printing speed of 5 mm s-1, PCL-DCM exhibited a Young's modulus of 39.0 MPa, while PCL-CF samples printed at 10 mm s-1 achieved the highest modulus of 32.0 MPa. Notably, when the printing speed was kept constant, applying higher pressures led to an increase in Young's modulus, suggesting that pressure plays a key role in enhancing scaffold stiffness. When comparing the 50% and 75% (w/v) polymer concentrations, the 50% (w/v) formulation stood out by offering both higher elongation and greater stiffness, which makes it particularly suitable for load-bearing applications. These findings provide a quantitative framework for optimizing extrusion-based bioprinting of PCL scaffolds, with implications for customized biomedical implants and regenerative medicine.Article Citation - WoS: 21Citation - Scopus: 38Fresh, Mechanical, Transport, and Durability Properties of Self-Consolidating Rubberized Concrete(Amer Concrete inst, 2012) Karahan, Okan; Ozbay, Erdogan; Hossain, Khandaker M. A.; Lachemi, Mohamed; Atis, Cengiz D.This paper presents the fresh, mechanical, transport, and durability performances of self-consolidating rubberized concretes (SCRCs). Fresh concrete properties were determined with slump flow, V-funnel, J-ring, and L-box tests. Mechanical, transport, and durability properties were determined by measuring compressive, flexural, and splitting tensile strengths; bond strength characteristics; water porosity; water absorption; water sorptivity; rapid chloride-ion permeability; and freezing-and-thawing and corrosion resistance. SCRC mixtures with a water-binder ratio (w/b) of 0.32; total binder content of 500 kg/m(3) (842 lb/yd(3)); and crumb rubber content of 0, 10, 20, and 30% by fine aggregate volume were produced and tested. Fresh properties testing revealed that the use of crumb rubber as a fine aggregate diminished the filling and passing ability of SCRC. A gradual reduction in mechanical properties was also observed with an increase in crumb rubber content; however, the rate of compressive strength reduction was more evident than that of tensile strength. Despite the fact that water porosity, water absorption, and chloride-ion permeability increased slightly with the use of crumb rubber, a remarkable decrease was observed in the initial and secondary water sorptivity of SCRC. No significant decrease was observed in the freezing-and-thawing and corrosion resistance of SCRC with 10% crumb rubber. Beyond that level, however, durability performance was significantly affected.