WoS İndeksli Yayınlar Koleksiyonu
Permanent URI for this collectionhttps://hdl.handle.net/20.500.12573/394
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Article Citation - WoS: 38Citation - Scopus: 38pH- and Temperature-Responsive Amphiphilic Diblock Copolymers of 4-Vinylpyridine and Oligoethyleneglycol Methacrylate Synthesized by RAFT Polymerization(Elsevier Sci Ltd, 2014-01) Topuzogullari, Murat; Bulmus, Volga; Dalgakiran, Eray; Dincer, SevilDiblock copolymers of 4-vinylpyridine (4VP) and oligoethyleneglycol methyl ether methacrylate (OEGMA) were synthesized for the first time using RAFT polymerization technique as potential drug delivery systems. Effects of the number of ethylene glycol units in OEGMA, chain length of hydrophobic P4VP block, pH, concentration and temperature on the solution behavior of the copolymers were investigated comprehensively. Copolymer chains formed micelles at pH values higher than 5 whereas unimeric polymers were observed to exist below pH 5, owing to the repulsion between positively charged P4VP blocks. The size of the micelles was dependent on the relative length of blocks, P4VP and POEGMA. Thermo-responsive properties of copolymers were investigated depending on the pH and length of P4VP block. The increase in the length of P4VP block decreased the LCST substantially at pH 7. At pH 3, LCST of copolymers shifted to higher temperatures due to the increased interaction of copolymers with water through positively charged P4VP block. (C) 2013 Elsevier Ltd. All rights reserved.Article Citation - WoS: 5Workplace Diversity and Intercultural Communication: A Phenomenological Study(Taylor & Francis As, 2017-01-01) Evans, Adam; Suklun, HarikaFor decades, the United States has seen an increasing number of immigrants, which has led to a significant increase in cultural diversity in the United States. This phenomenological study examines the contextual history of professional non-native English-speaking women in the United States to form a basis of comparison with native English speakers. It attempts to compare their lived communicative experiences with those of non-native English speakers in the workplace. In this study, 16 professional, native English-speaking women currently working in the US were interviewed. Participants in this study were asked to describe professional and intercultural experiences through interactions with non-native English-speaking coworkers, any expectations of the interactions or violations of those expectations, and any miscommunications that may have occurred. Many native English speakers positively reflected upon these intercultural interactions and shared examples of their vocal adjustments and challenges of verbal and intercultural communication. To overcome these challenges, professional native English speakers described trying to slow speech or asking confirming questions such as Do you understand? to mitigate verbal conflicts and miscommunication. Based on the trends within the responses, however, there is a potential for unintentional and often offensive consequences to occur. Several coping mechanisms were found to be considered rude or off-putting by non-native speakers, while the intent of a more direct message was often misinterpreted by native English speakers. In addition, it seems that native English speakers often may have good intentions in their actions but do not have the skillset to better facilitate communication with non-native English speakers.Article Citation - WoS: 24Citation - Scopus: 26Wireless Measurement of Elastic and Plastic Deformation by a Metamaterial-Based Sensor(MDPI, 2014-10-20) Ozbey, Burak; Demir, Hilmi Volkan; Kurc, Ozgur; Erturk, Vakur B.; Altintas, AyhanWe report remote strain and displacement measurement during elastic and plastic deformation using a metamaterial-based wireless and passive sensor. The sensor is made of a comb-like nested split ring resonator (NSRR) probe operating in the near-field of an antenna, which functions as both the transmitter and the receiver. The NSRR probe is fixed on a standard steel reinforcing bar (rebar), and its frequency response is monitored telemetrically by a network analyzer connected to the antenna across the whole stress-strain curve. This wireless measurement includes both the elastic and plastic region deformation together for the first time, where wired technologies, like strain gauges, typically fail to capture. The experiments are further repeated in the presence of a concrete block between the antenna and the probe, and it is shown that the sensing system is capable of functioning through the concrete. The comparison of the wireless sensor measurement with those undertaken using strain gauges and extensometers reveals that the sensor is able to measure both the average strain and the relative displacement on the rebar as a result of the applied force in a considerably accurate way. The performance of the sensor is tested for different types of misalignments that can possibly occur due to the acting force. These results indicate that the metamaterial-based sensor holds great promise for its accurate, robust and wireless measurement of the elastic and plastic deformation of a rebar, providing beneficial information for remote structural health monitoring and post-earthquake damage assessment.Article Citation - WoS: 25Citation - Scopus: 33Volume Fraction, Thickness, and Permeability of the Sealing Layer in Microbial Self-Healing Concrete Containing Biogranules(Frontiers Media S.A., 2018-11-23) Ersan, Yusuf Cagatay; Palin, Damian; Tasdemir, Sena Busra Yengec; Tasdemir, Kasim; Jonkers, Henk M.; Boon, Nico; De Belie, Nele; Yengec Tasdemir, Sena BusraAutonomous repair systems in construction materials have become a promising alternative to current unsustainable and labor-intensive maintenance methods. Biomineralization is a popular route that has been applied to enhance the self-healing capacity of concrete. Various axenic microbial cultures were coupled with protective carriers, and their combination appears to be useful for the development of healing agents for realizing self-healing concrete. The advantageous traits of non-axenic cultures, such as economic feasibility, self-protection, and high specific activity have been neglected so far, and thus the number of studies investigating their performance as healing agents is scarce. Here we present the self-healing performance of a mortar containing a healing agent consisting of non-axenic biogranules with a denitrifying core. Mortar specimens with a defined crack width of 400 mu m were used in the experiments and treated with tap water for 28 days. Self-healing was quantified in terms of the crack volume reduction, the thickness of the sealing layer along the crack depth and water permeability under 0.1 bar pressure. Complete visual crack closure was achieved in the bio-based specimens in 28 days, the thickness of the calcite layer was recorded as 10 mm and the healed crack volume was detected as 6%. Upon self-sealing of the specimens, the water permeability decreased by 83%. Overall, non-axenic biogranules with a denitrifying core shows great potential for development of self-healing bioconcrete.Article Citation - WoS: 24Citation - Scopus: 33Variable Structure Controllers for Unstable Processes(Elsevier Sci Ltd, 2015-08) Ablay, GunyazA variable structure control (VSC) method for unstable industrial processes is proposed. The proposed control method is able to provide a highly satisfactory system performance and to tackle with robustness issues of the processes in the presence of uncertainties. An ITAE-based numerical tuning algorithm for acquiring optimal control parameters, and a direct auto-tuning mechanism for the proposed controller are also provided. The performance of the proposed VSC method is illustrated on some unstable process models including a continuous stirred tank reactor (CSTR), in order to show its effectiveness, validity and feasibility. (C) 2015 Elsevier Ltd. All rights reserved.Article Citation - WoS: 15Citation - Scopus: 14Understanding Plasmon Coupling in Nanoparticle Dimers Using Molecular Orbitals and Configuration Interaction(Royal Soc Chemistry, 2019) Alkan, Fahri; Aikens, Christine M.We perform a theoretical investigation of the electronic structure and optical properties of atomic nanowire and nanorod dimers using DFT and TDDFT. In both systems at separation distances larger than 0.75 nm, optical spectra show a single feature that resembles the bonding dipole plasmon (BDP) mode. A configuration interaction (CI) analysis shows that the BDP mode arises from constructive coupling of transitions, whereas the destructive coupling does not produce significant oscillator strength for such separation distances. At shorter separation distances, both constructive and destructive coupling produce oscillator strength due to wave-function overlap, which results in multiple features in the calculated spectra. Our analysis shows that a charge-transfer plasmon (CTP) mode arises from destructive coupling of transitions, whereas the BDP results from constructive coupling of the same transitions at shorter separation distances. Furthermore, the coupling elements between these transitions are shown to depend heavily on the amount of exact Hartree-Fock exchange (HFX) in the functional, which affects the splitting of CTP and BDP modes. With 50% HFX or more, the CTP and BDP modes mainly merge into a single feature in the spectra. These findings suggest that the effects of exact exchange must be assessed during the prediction of CTP modes in plasmonic systems.Article Citation - WoS: 33Citation - Scopus: 32Unconfined Compressive Strength and Freeze-Thaw Resistance of Sand Modified With Sludge Ash and Polypropylene Fiber(Techno-press, 2017) Gullu, Hamza; Fedakar, Halil I.In recent years, the amount of sludge ash (SA) has considerably increased due to rapid urbanization and population growth. In addition, its storage in landfills induces environmental pollution and health problems. Therefore, its disposal in an environmentally friendly way has become more important. The main goal of this study is to investigate the reusability of sludge ash as an additive with polypropylene fiber (PF) to stabilize marginal sand based on the compressive strength performances from UCS tests. For this purpose, a series of UCS tests was conducted. Throughout the experimental study, the used inclusion rates were 10, 15, 20 and 30% for sludge ash and 0, 0.5 and 1% for polypropylene fiber by total dry weight of the sand+sludge ash mixture and the prepared samples were cured for 7 and 14 days prior to the testing. Freezing and thawing resistance of the mixture including 10% sludge ash and 0, 0.5 and 1% polypropylene fiber was also examined. On the basis of UCS testing results, it is said that sludge ash inclusion remarkably enhances UCS performance of sand. Moreover, the addition of polypropylene fiber to the admixtures including sand and sludge ash significantly improves their stress-strain characteristics and post-peak strength loss as well as UCS. As a result of this paper, it is suggested that sludge ash be successfully reused with polypropylene fiber for stabilizing sand in soil stabilization applications. It is also believed that the findings of this study will contribute to some environmental concerns such as the disposal problem of sludge ash, recycling, sustainability, environmental pollution, etc. as well as the cost of an engineering project.Article Citation - WoS: 1Citation - Scopus: 1Triple Positive Solutions of M-Point Boundary Value Problem on Time Scales With P-Laplacian(Iranian Mathematical Soc, 2017) Dogan, A.In this paper, we consider the multipoint boundary value problem for one-dimensional p-Laplacian dynamic equation on time scales. We prove the existence at least three positive solutions of the boundary value problem by using the Avery and Peterson fixed point theorem. The interesting point is that the non-linear term f involves a first-order derivative explicitly. Our results are new for the special cases of difference equations and differential equations as well as in the general time scale setting.Article Citation - WoS: 2Citation - Scopus: 7Triple Positive Solutions for M-Point Boundary-Value Problems of Dynamic Equations on Time Scales With P-Laplacian(Texas State Univ, 2015) Dogan, AbdulkadirIn this article we study the existence of positive solutions for m-point dynamic equation on time scales with p-Laplacian. We prove that the boundary-value problem has at least three positive solutions by applying the five functionals fixed-point theorem. An example demonstrates the main results.Article Citation - WoS: 31Citation - Scopus: 35Transmitter Localization in Vessel-Like Diffusive Channels Using Ring-Shaped Molecular Receivers(IEEE-Inst Electrical Electronics Engineers Inc, 2018-12) Turan, Meric; Akdeniz, Bayram Cevdet; Kuran, Mehmet Comma Sukru; Yilmaz, H. Birkan; Demirkol, Ilker; Pusane, Ali E.; Tugcu, Tuna; Birkan Yilmaz, H.Molecular communication via diffusion in vessellike environment targets critical applications such as the detection of abnormal and unhealthy cells. In this letter, we derive the analytical formulation of the channel model for diffusion dominated movement, considering ring-shaped (i. e., patch) observing receivers, and Poiseuille flow with the aim of localization of the transmitter cell. Then, we derive formulations using this channel model for two different application scenarios. We assume that the emission start time is known in the first scenario and unknown in the second one. We successfully localize the transmitter cell using a single receiver for the first scenario, whereas two receivers are used to localize the transmitter cell in the second scenario. At last, the devised analytical framework is validated with simulations.