WoS İndeksli Yayınlar Koleksiyonu
Permanent URI for this collectionhttps://hdl.handle.net/20.500.12573/394
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Article Citation - WoS: 6Citation - Scopus: 10The Size and Concentration Effects of Al2O3 Nanoparticles on PSF Membranes With Enhanced Structural Stability and Filtration Performance(Desalination Publ, 2017-07) Saki, Seda; Uzal, Nigmet; Ates, NurayNanocomposite membranes have attracted attention for their high permeability, rejection efficiency, and thermal and mechanical stability. In this study, novel flat-sheet polysulfone nanocomposite membranes were prepared by a phase inversion method with polyethylenimine and Al2O3 nanoparticles to increase the flux and hydrophilicity. Al2O3 nanoparticles were added to the membrane matrix to enhance the permeability, selectivity, and mechanical resistance. Two different sizes of Al2O3 nanoparticles (20 and 80 nm) were used with different weight percentages of 0.2, 1, and 5 wt%. The effects of the size and concentration of the nanoparticles on the structural properties and filtration performance of the membranes were investigated. Scanning electron microscopy, Fourier transform infrared spectroscopy, porosity, water contact angle, thermogravimetric analysis, viscosity, and tensile strength measurements were used to characterize the prepared membranes. The membrane performance was evaluated with water flux and bovine serum albumin rejection tests. According to the results, the membrane containing 15 wt% polysulfone, 1 wt% polyethylenimine, and 5 wt% 20 nm Al2O3 showed the highest pure water flux, porosity, viscosity, and morphological stability. This membrane may have potential uses in water treatment applications.Article Citation - WoS: 60Citation - Scopus: 66Preparation and Characterization of PSF/PEI Nanocomposite Membranes for Oil/Water Separation(Springer Heidelberg, 2018-06-26) Saki, Seda; Uzal, NigmetUltrafiltration (UF) is one of the significant advanced processes for oily wastewater treatment due to its clear advantages, for instance, ease in operation and efficient separation. The main drawback of these processes is the fouling problem and many researchers' effort on fabrication of high-performance membranes with higher hydrophilicity and antifouling properties. In this study, flat-sheet polysulfone (PSF)/polyethylenimine (PEI)/CaCO3 nanocomposite membranes were prepared by phase inversion method for oil/water emulsion separation. Structural properties of membranes were characterized by SEM, FT-IR, contact angle, tensile strength, and atomic force microscopy analysis. Increasing the CaCO3 nanoparticle loading exhibited the increased the water flux and BSA rejection. PSF/PEI/10 wt% CaCO3 nanocomposite membranes have 145 L/m(2) h water flux at 2 bar with a contact angle of 84 degrees and with 92% BSA rejection. All prepared CaCO3 nanocomposite membranes reached similar oil rejections at above 90%. Besides the higher water flux and oil removal efficiencies, 10 wt% of CaCO3 nanoparticle-blended PSF membranes has notable antifouling capacity with the highest flux recovery ratio (FRR) and lowest flux decay ratio (DR) values. The results showed that there is a great potential to use PSF/PEI/CaCO3 nanocomposite membranes for the treatment of oil water emulsions with higher permeability and antifouling capacity.Article Citation - WoS: 17Citation - Scopus: 24Clarification of Apple Juice Using New Generation Nanocomposite Membranes Fabricated With TiO2 and Al2O3 Nanoparticles(Springer, 2019-11-26) Severcan, Solmaz Sebnem; Uzal, Nigmet; Kahraman, KevserTo enhance anti-fouling properties of polymeric membranes during apple juice clarification, PSF/PEI (20/2 wt%) ultrafiltration (UF) membranes were modified with TiO2 and Al2O3 nanoparticles using the phase inversion method. Turbid apple juice samples were clarified using cross-flow membrane filtration system. All fabricated nanocomposite UF membranes had higher apple juice flux values than PSF/PEI membrane. Membrane prepared with 0.01% TiO2 (UFT1) had the highest apple juice flux (at steady state, 44.6 L/m(2)h). The FRR (%) value of TiO2 and Al2O3 incorporated UF membranes was between 90.9-94.0% and 79.6-97.6%, respectively, and these FRR values were higher than that of PSF/PEI membrane (UF2, 60.3%). Porosity and hydrophilicity of the UF membranes significantly increased with the addition of nanoparticles and the highest porosity and hydrophilicity was achieved in the 0.01% TiO2 incorporated UF membrane (UFT1) membrane. Higher flux recovery ratio (FRR) and lower relative flux reduction (RFR) values of Al2O3 and TiO2 incorporated nanocomposite membranes, compared with the unmodified membrane, demonstrated the enhancement in the anti-fouling properties of the PSF/PEI membrane. SEM images of the nanocomposite membranes also proved the nanoparticle incorporation to the PSF/PEI matrix. Color, turbidity, total soluble solid, total phenolic content, and antioxidant capacity of the samples using nanocomposite membranes were better than that of clarified using both commercial and unmodified membranes. TiO2 incorporated nanocomposite membranes had superior performance than Al2O3 incorporated nanocomposite membranes and among these membranes, the ones prepared with the addition of 0.01 wt% TiO2 exhibit the best performance in terms of clarification of apple juice.