WoS İndeksli Yayınlar Koleksiyonu
Permanent URI for this collectionhttps://hdl.handle.net/20.500.12573/394
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Article Citation - WoS: 9Citation - Scopus: 9Reaction Kinetics and Properties of Pumice-Based Geopolymer Systems Cured at Room Temperature(Elsevier Sci Ltd, 2023-12) Kucukyildirim, Enver; Yorulmaz, Hediye; Durak, Ugur; Ilkentapar, Serhan; Uzal, Burak; Karahan, Okan; Atis, Cengiz DuranThis research investigated the kinetics of pumice-based geopolymer systems and their physical and mechanical properties. The effect of the Na2SiO3/NaOH ratio of geopolymer systems on the rate of heat evolution and total heat of reaction were examined via isothermal calorimetry of geopolymer pastes prepared with Na2SiO3/NaOH ratios of 2.5, 3, and 3.5. Hardened pastes were also studied with thermo-gravimetric analysis to determine weight loss. In addition, the unit weights and compressive strengths of the pastes prepared using pumice were measured. Although the hydration process starts the earliest in pumice-based geopolymer pastes with a Na2SiO3/ NaOH ratio of 2, they have the lowest total hydration temperature. Na2SiO3/NaOH ratio of 2.5 by mass, shows higher weight loss obtained from TGA results. The compressive strength of the paste sample, prepared with a Na2SiO3/NaOH ratio of 3.5 by mass, was the highest, with 36.30 MPa at 28d. Depending on the Na2SiO3/NaOH ratio, it is thought that as the amount of Na2SiO3 increases in the samples, silica gel formation increases in later ages.Article Citation - WoS: 127Citation - Scopus: 138Influence of Admixtures on the Properties of Alkali-Activated Slag Mortars Subjected to Different Curing Conditions(Elsevier Sci Ltd, 2013-02) Bilim, Cahit; Karahan, Okan; Atis, Cengiz Duran; Ilkentapar, SerhanThis paper presents the influence of shrinkage-reducing (SHR) and superplasticizing and set-retarding admixtures (SSRe) on the properties of slag pastes and mortars activated by liquid sodium silicate with different dosage and modulus ratio. Properties in the fresh and hardened state for these binders were investigated by means of measuring some properties including setting time, flowability, flexural strength, compressive strength, carbonation and shrinkage. In this study, fifteen pastes and mortars were prepared. Liquid sodium silicate was used to activate the slag at two sodium concentrations, 4% and 6% by mass of slag. Liquid sodium silicate and sodium hydroxide were blended to obtain 0.75 and 1 modulus ratio of SiO2/Na2O. Results showed that although the higher percentage of sodium in the activator produced a higher strength, workability and setting times rapidly decreased with the higher sodium concentration due to instantaneous reaction and quick hardening of slag activated by liquid sodium silicate. None of the admixtures generally had an impact on the setting times of alkali-activated slag (AAS) pastes. SSRe admixture increased the flow rate of AAS mortars while SHR admixture partially affected the flow values of AAS mortars. SHR admixture exhibited a slight decrease in the carbonation depths of AAS mortars. SSRe and particularly SHR chemical admixtures reduced the shrinkage of AAS mortars. However, the shrinkage values of AAS mortars still were higher than those of ordinary Portland cement (NPC) mortars. Curing conditions had a significant effect on the mechanical behavior in the hardened state of AAS mortars compared to NPC mortars. (C) 2012 Elsevier Ltd. All rights reserved.Article Citation - WoS: 108Citation - Scopus: 124Dual Effectiveness of Freezing-Thawing and Sulfate Attack on High-Volume Slag-Incorporated ECC(Elsevier Sci Ltd, 2013-02) Ozbay, Erdogan; Karahan, Okan; Lachemi, Mohamed; Hossain, Khandaker M. A.; Atis, Cengiz DuranThis study investigated the dual effect of freeze-thaw cycles with sodium sulfate solution on the performance of non-air-entrained Engineering Cementitious Composites (ECCs) with high volumes of slag. ECC specimens containing three different levels of slag content as a replacement for cement (55%, 69% and 81% by weight of total cementitious material) were exposed to aggressive sodium sulfate solution under freezing-thawing cycles. The load-deflection response associated with ultimate mid-span deflection and flexural strength/stiffness was determined, along with crack development behavior. For comparison purposes, the freezing-thawing resistance (in water) of control ECC specimens was also evaluated. Modified point count method air-void parameters, compressive strength, porosity, water absorption and sorptivity tests were also conducted on the virgin ECC specimens (those not exposed to freezing-thawing cycles in water or aggressive sodium sulfate solution). The test results for the virgin specimens revealed that increased slag content (S/PC) improved the ductility, hardened air content, water absorption, porosity and sorptivity of ECC, while marginally decreasing the compressive and flexural strengths. Freeze-thaw cycles in water or sodium sulfate solution showed that the ductility of ECC specimens decreased remarkably, irrespective of slag content and applied freezing-thawing process. Reduction in mass loss was at minimal levels and no significant behavior change was monitored between the specimens undergoing freeze-thaw cycling in water and the aggressive sodium sulfate solution. Moreover, the decrease in flexural stiffness was more evident than the reduction of the flexural strength for all ECC mixtures. Crown Copyright (c) 2012 Published by Elsevier Ltd. All rights reserved.