WoS İndeksli Yayınlar Koleksiyonu
Permanent URI for this collectionhttps://hdl.handle.net/20.500.12573/394
Browse
2 results
Search Results
Article Citation - WoS: 8Citation - Scopus: 8Writing Chemical Patterns Using Electrospun Fibers as Nanoscale Inkpots for Directed Assembly of Colloidal Nanocrystals(Royal Soc Chemistry, 2020) Kiremitler, N. Burak; Torun, Ilker; Altintas, Yemliha; Patarroyo, Javier; Demir, Hilmi Volkan; Puntes, Victor F.; Onses, M. SerdarApplications that range from electronics to biotechnology will greatly benefit from low-cost, scalable and multiplex fabrication of spatially defined arrays of colloidal inorganic nanocrystals. In this work, we present a novel additive patterning approach based on the use of electrospun nanofibers (NFs) as inkpots for end-functional polymers. The localized grafting of end-functional polymers from spatially defined nanofibers results in covalently bound chemical patterns. The main factors that determine the width of the nanopatterns are the diameter of the NF and the extent of spreading during the thermal annealing process. Lowering the surface energy of the substrates via silanization and a proper choice of the grafting conditions enable the fabrication of nanoscale patterns over centimeter length scales. The fabricated patterns of end-grafted polymers serve as the templates for spatially defined assembly of colloidal metal and metal oxide nanocrystals of varying sizes (15 to 100 nm), shapes (spherical, cube, rod), and compositions (Au, Ag, Pt, TiO2), as well as semiconductor quantum dots, including the assembly of semiconductor nanoplatelets.Article Citation - WoS: 3Citation - Scopus: 3Excitonic Interaction Amongst InP/ZnS Salt Pellets(Royal Soc Chemistry, 2017) Altintas, Yemliha; Yazici, Ahmet Faruk; Unlu, Miray; Dadi, Seyma; Genc, Sinan; Mutlugun, Evren; Faruk Yazici, AhmetSalt matrix has recently been introduced as a promising robust platform for embedding colloidal quantum dots to provide them with photo stability for versatile applications. This work demonstrates the excitonic interaction amongst high efficiency colloidal InP/ZnS quantum dots embedded in a KCl salt matrix. By varying the donor acceptor ratio within the solid platform, 65% Forster Resonance Energy Transfer (FRET) efficiency was attained. Optimizing the donor : acceptor ratio, we demonstrated the first FRET-enabled Cd-free pellets for white light generation possessing a color rendering index (CRI) of 84.7, correlated color temperature (CCT) of 5347.5 K, and a high luminous efficacy of optical radiation value (LER) of 324.3 lm/W-opt. Our study of excitonic interactions within quantum dot-loaded salt matrices will open new possibilities for future versatile optoelectronic applications.