WoS İndeksli Yayınlar Koleksiyonu
Permanent URI for this collectionhttps://hdl.handle.net/20.500.12573/394
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Article Citation - WoS: 2Citation - Scopus: 2A Novel Biomass-Derived Reductant for Nitric Acid Dissolution of Manganiferous Iron Ore: Comparative Assessment of Organic Reductants(MDPI, 2025-12-31) Top, Soner; Altiner, Mahmut; Vapur, Huseyin; Kursunoglu, Sait; Stopic, SreckoThis study investigates the selective dissolution of manganese from a manganiferous iron ore using nitric acid (HNO3) in the presence of various organic reductants. A series of leaching experiments was performed to evaluate the effects of temperature, reductant type, and leaching time on Mn recovery, with particular emphasis on biomass (horse dung) and tartaric acid as novel reducing agents. The dissolution behaviour of Fe, Mn, Mg, Ca, and Al was systematically examined, revealing that Mn extraction was strongly enhanced in the presence of reductants, while Fe dissolution remained below 10% under all conditions. The maximum Mn dissolution exceeded 90% at 90 degrees C using biomass and reached nearly 85%-90% with tartaric acid at elevated temperatures. Kinetic studies were conducted by applying reaction order models and the shrinking core model. The results indicated that Mn dissolution in HNO3 medium is predominantly controlled by surface chemical reaction, with Arrhenius analysis yielding activation energies of 27.74 kJ/mol for biomass and 21.26 kJ/mol for tartaric acid. These relatively low values confirm the efficiency of organic reductants in facilitating Mn reduction and dissolution. To sum up, comparison of reductant efficiency revealed that, at the lowest concentrations, the dissolution of Mn followed the sequence glucose > sucrose > oxalic acid > tartaric acid > maleic acid > biomass > citric acid > acetic acid. At the highest concentrations, the trend shifted, with citric acid emerging as the most effective, followed by tartaric acid > oxalic acid > glucose > sucrose > maleic acid > biomass > acetic acid.Article Citation - WoS: 1Citation - Scopus: 1A Comprehensive Review on the Extraction and Recovery of Lithium from Primary and Secondary Sources: Advances Toward Battery-Grade Materials(Wiley, 2025-10-20) Top, Soner; Kursunoglu, Sait; Altiner, MahmutLithium-ion battery (LIB) technologies have become indispensable to modern energy systems, driving global demand for high-purity lithium compounds. This review focuses on lithium recovery and purification strategies for battery-grade lithium carbonate (Li2CO3) and lithium hydroxide (LiOH), addressing both primary sources (brines and minerals) and secondary sources (waste materials). Industrially established processes, such as evaporation-based brine treatment and conventional metallurgical methods, are discussed alongside emerging techniques, including membrane separation, solvent extraction, and CO2-assisted precipitation. Particular attention is given to lithium precipitation mechanisms, the behaviour of co-existing ions during extraction, and the specific quality requirements for cathode material synthesis. By evaluating process scalability, environmental impact, and product purity, this review provides a comprehensive understanding of current practices and future directions. Additionally, it highlights the growing importance of lithium in the context of accelerating electric vehicle (EV) adoption, underscoring the bright and expanding future of the lithium industry.Article Citation - WoS: 4Citation - Scopus: 3Recovery of Vanadium and Nickel From a High Caco3 Containing Petroleum Coke Ash by Roasting and Acidic Leaching(Springer, 2023-11-08) Yurtseven, Ozgun; Ibrahim, Ahmedaljaali Ibrahim Idrees; Top, Soner; Kursunoglu, Sait; Altiner, MahmutIn this study, it was aimed to extract vanadium (V) and nickel (Ni) from a petroleum coke ash (PCA) using a roasting process without additives, followed by leaching with sulfuric acid (H2SO4). The experiments were designed based on the Taguchi approach, taking into account the parameters of temperature, acid concentration, time, and solid ratio. Additional leaching tests were conducted on the non-roasted PCA for comparison, to assess the effect of roasting on the extractions of V and Ni. The results showed that no extra reducing agent was needed as the PCA contained high levels of CaCO3, which could be used as a reducing agent during roasting. It was found that roasting was essential for high Ni extractions, but had no strong effects on V extractions. The Ni extraction was found to be between 13.3 and 80.8% for the non-roasted PCA and between 43.6 and 99.3% for the roasted PCA. The V extraction was between 36 and 97.9% for the non-roasted PCA and between 45.4 and 99.9% for the roasted PCA. The optimal leaching conditions were determined to be a sulfuric acid of 4.5 M, a solid ratio of 10%, a temperature of 75 degrees C, and a time of 75 min. In addition, it was determined that the leaching conditions had a great effect on the oxidation state of vanadium ions, and an increase in the acid concentration led to the formation of V3+ ions (green color) instead of VO2+ ions (blue color) in the pregnant leach solution. The final pregnant leach solution containing 1056.50 mg/L V, and 251.85 mg/L Ni was achieved with an extraction yields of > 98%. The experimental results were greatly fitted by the shrinking core model and the activation energy (E-a) for V and Ni was calculated as 3.60 and 4.01 kJ/mol, indicating that the leaching mechanism can be explained by the diffusion control model.Article Citation - WoS: 4Citation - Scopus: 4Beneficiation of Low-Grade Iron Ore Using a Dry-Roll Magnetic Separator and Its Modeling via Artificial Neural Network(Springer, 2025-02-24) Fariss, Abdourahman Hassan Brahim; Ibrahim, Ahmedaljaali Ibrahim Idrees; Ozdemir, Ali Can; Top, Soner; Kursunoglu, Sait; Altiner, MahmutThe beneficiation of low-grade iron ore (39.5% Fe-(T) grade) using a dry-roll magnetic separator was investigated. The ore was characterized using Mineral Liberation Analysis (MLA). It was determined that the ore was composed of iron oxide (goethite and hematite), quartz, chlorite, muscovite, plagioclase, and other minerals. The effect of particle size (PS, - 1 + 0.500 mm, - 0.500 + 0.300 mm, and - 0.300 + 0.125 mm), splitter position (SP, 43 degrees and 58 degrees), cleaning stage (CS, 1 and 2), conveyor speed (CoS, 3, 5, and 7 Hz), magnetic field strength (MFS, 0.2 T and 0.4 T) on the recovery of the magnetic product was investigated. Experimental results show that the product (- 1 + 0.500 mm) with the Fe-(T) grade of 67.67% can be obtained, but its recovery was not at an acceptable value (< 30%). Furthermore, the Fe-(T) grade of the product (- 0.500 + 0.300 and - 0.300 + 0.125 mm) could not reach satisfactory levels<bold>.</bold> The artificial neural network (ANN) method was conducted on the results of experimental studies. Three different training algorithms were employed for modeling, and their performance was assessed using statistical evaluation criteria. The results demonstrate that Bayesian Regularization (BR) algorithm exhibited better performance compared to others in predicting both Fe(T) grade and recovery rate during the testing phase. These findings support the notion that ANN algorithms can be a powerful modeling and prediction tool in the field of mineral processing.Article Citation - WoS: 2Citation - Scopus: 1A Review on the Recovery of High-Grade Critical Metals From Spent Petroleum Catalysts for Meeting the Demands of Industry 5.0(Taylor & Francis inc, 2024-03-22) Taz, Dilara; Ozsarac, Safak; Kursunoglu, Sait; Kursunoglu, Nilufer; Top, Soner; Altiner, MahmutIn solvent extraction studies, various extractants, including TOPO, Alamine 308, TBP, TOA, LIX 84I, LIX 63, and Aliquat 336, were employed for the extraction and separation of vanadium, molybdenum, and cobalt from aqueous solutions of spent petroleum catalysts. Results indicated efficient metal recovery using these extractants. Furthermore, a combination of techniques, such as roasting, chemical or bioleaching, solvent extraction (SX), and precipitation, exhibited promising results in achieving comprehensive metal extraction and separation. Important discoveries have been made in the study of recovering important metals from wasted petroleum catalysts, especially with regard to attaining high metal recovery efficiencies. It is found that the recovery efficiency for manganese is 85%, cobalt is 87%, and nickel is 93%. Furthermore, it shows that this procedure may be carried out with high efficiency, with vanadium recovery surpassing 90% and molybdenum recovery efficiency above 95%. These outcomes signify a significant advancement in the field of metal extraction and separation, aligning with the principles of Industry 5.0 while emphasizing sustainability and efficiency in the production of high-tech materials for the modern era.Article A Distinctive Determination of Circular Nozzles in Downcomer for Column Flotation(Taylor & Francis inc, 2023-01-07) Vapur, Huseyin; Top, Soner; Altiner, MahmutThis study aims to recover clean coal from valuable hard coal tailings (HCT), which have been used as solid fuels in a thermal power plant, through convenient conditions. The effective diameters of circular nozzles on the recovery of HCT were investigated by using the Jameson cell (JC) as the main purpose. Preliminary tests were conducted to determine the type and dosages of the collector and frother. The JC test results were evaluated by Yates and Box Behnken based on ANOVA analysis, statistically. It was observed that 3,000 g/ton of diesel oil, 300 g/ton of MIBC, 100 g/ton of Na2SiO3, and 60 cm of downcomer depth were found applicable levels of parameters. The decrease of the diameter increased the venturi effect of downcomer which provided the best recovery ratio of 97.79%. Besides, the results of kinetic models were obtained with desired efficiencies (CR infinity = 94.77%, k(coal) = 1.20, R-2 = 0.98 and SI = 2.40). The best diameter was 5 cm supplied a short time and high carrying capacity (CC) for concentrate.