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Browsing by Author "Mutlugün, E."

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    Article
    Colloidal Photodetectors Based on Engineered Multishelled InP Based Quantum Dots
    (Institute of Physics, 2026) Akrema; Erol, E.; Savaş, M.; Yazici, A.; Erdem, T.; Mutlugün, E.; Faruk Yazıcı, Ahmet
    In this work, we present a straightforward and cost-effective approach to synthesize multi-shell InP/ZnSe/ZnSeS/ZnS quantum dots (QDs) that show promising potential for use in photodetectors. By carefully layering ZnSe, ZnSeS, and ZnS shells around an InP core, we were able to enhance the stability and optical performance of the QDs, achieving a narrow emission peak of 45 nm and a high photoluminescence quantum yield of 55%. These QDs were then integrated into simple photodetector devices, which possessed impressive sensitivity and detection capabilities. Specifically, our devices achieved a peak responsivity of 0.54 A W−1 and a detectivity of 2.22 × 1011 Jones at 400 nm with a 5 V bias. This study highlights the potential of InP-based QDs as a safer and more sustainable alternative to traditional QDs that contain toxic heavy metals, offering a viable path forward for developing high-performance optoelectronic devices. Our findings suggest that these InP/ZnSe/ZnSeS/ZnS QDs could be a key material for the next generation of high-performance optoelectronic devices, especially in applications that require highly sensitive and stable photodetectors. © 2026 The Author(s). Published by IOP Publishing Ltd.
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    Erratum
    Correction to “Multifaceted Effects of the Dielectric Component within Plasmon-Assisted Light-Emitting Structures”
    (American Chemical Society, 2026) Kulakovich, O.; Muravitskaya, A.; Ramanenka, A.; Efimova, T.; Krukov, V.; Mutlugün, E.; Gaponenko, S.
    In the original version of the article, the affiliation of Hilmi Volkan Demir needs following correction. The first affiliation of the author “Department of Electrical-Electronics Engineering, Abdullah Gul University, Kayseri 38080, Turkey” should be replaced by the affiliation “UNAM – Institute of Materials Science and Nanotechnology and The National Nanotechnology Research Center and Department of Electrical and Electronics Engineering, Department of Physics, Bilkent University, Ankara 06800, Turkey”. Therefore, the correct affiliations for H.V.D. are “UNAM – Institute of Materials Science and Nanotechnology and The National Nanotechnology Research Center and Department of Electrical and Electronics Engineering, Department of Physics, Bilkent University, Ankara 06800, Turkey; LUMINOUS! Center of Excellence for Semiconductor Lighting and Displays, School of Electrical and Electronic Engineering, School of Physical and Mathematical Sciences, School of Materials Science and Engineering, Nanyang Technological University, Singapore 639798, Singapore”. © 2025 American Chemical Society
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    Citation - Scopus: 2
    Multifaceted Effects of the Dielectric Component Within Plasmon-Assisted Light-Emitting Structures
    (American Chemical Society, 2025) Kulakovich, O.; Muravitskaya, A.; Ramanenka, A.; Efimova, T.; Krukov, V.; Mutlugün, E.; Gaponenko, S.
    Plasmon-enhanced photoluminescence of molecular probes and semiconductor nanocrystals is a rapidly developing field that promises enhanced sensitivity in chemical and biomedical analyses, as well as higher efficiency of light-emitting devices and single-photon sources. The dielectric component, or spacer, is typically used to control the distance between the emitter and the plasmonic nanoparticle in order to decrease undesirable nonradiative energy transfer to the metal and achieve high enhancement efficiency. While most research focuses on the shape and organization of the plasmonic nanoparticles, less attention is given to the role of the dielectric component in plasmon-enhancing structures. Meanwhile, the dielectric shell or environment critically modulates near-field enhancement, far-field scattering, charge and energy exchange between the emitter and the plasmonic structure, and the general environmental stability of the structure. In this review, we discuss all mentioned topics and therefore consider both the optical and chemical influence of the widely used spacers and dielectric layers on plasmon-enhanced photoluminescence efficiency. Investigating the role of individual components in plasmon-assisted light-emitting structures is critical for optimizing device performance and for advancing the integration of plasmonic architectures in optoelectronic and sensing applications. This review challenges the passive interpretation of dielectrics, revealing them as one of the key players in plasmonic structures, mediating field enhancement, emission dynamics, and chemical stability simultaneously. © 2025 American Chemical Society
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    Photoluminescent Carbon Dots for Sensitive and Selective Cu2+ Ion Detection
    (Institute of Physics, 2026) Sahin-Tiras, K.; Karabel Ocal, S.; Mutlugün, E.; Sahin Tiras, Kevser
    Green-emitting carbon dots (CDs) were synthesized via a solvent-free, vacuum-assisted method using citric acid and urea. The CDs exhibited strong photoluminescence and served as selective, sensitive probes for Cu2+ detection in water, with a detection limit of 26 nM. Among the tested metal ions, Cu2+ induced the most significant PL quenching. Time-resolved photoluminescence measurements of the CDs in the presence of Cu2+ ions revealed a minimal change in lifetime, despite a significant decrease in PL intensity, along with unchanged UV-vis absorption, indicating a mixed quenching mechanism. The sensor’s applicability was confirmed in raisin extract and tea infusion, showing notable PL suppression. With their simplicity, selectivity, and sensitivity, these CDs offer promising potential as nanosensors for detecting Cu2+ in environmental and real-world analytical settings. © 2026 The Author(s). Published by IOP Publishing Ltd.
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