Yavuz, Mustafa SelmanCitir, Murat2025-09-252025-09-2520220170-08391436-2449https://doi.org/10.1007/s00289-021-03809-4https://hdl.handle.net/20.500.12573/3937Yavuz, Mustafa Selman/0000-0002-6436-6373;In this study, we synthesized an aliphatic-aromatic regular network as a novel covalent organic networks called TEPN-1 (Thiol-ene Polymer Network) and TEPN-2 via thiol-ene chemistry. TEPN-1 and TEPN-2 were analyzed by FTIR, C-13-NMR, Brunauer-Emmett-Teller, thermogravimetric analysis and elemental analysis. Solvent uptake capacity of TEPN-1 and TEPN-2 was employed against 26 solvents which are frequently used in chemical industry. It is found that TEPN-1 has the highest swelling adsorption ratio with chloroform and DCM (13.7 and 11.5 g.g(-1), respectively), while TEPN-2 has 9.2 and 7.5 g.g(-1), respectively. Both TEPN-1 and TEPN-2 have very minimal water uptake (0.165 and 0.189 g.g(-1), respectively). TEPN-1 and TEPN-2 are efficient adsorbents for most of organic solvents including water-miscible organic solvents such as THF, dioxane and pyridine.eninfo:eu-repo/semantics/closedAccessSolvent UptakeCovalent Organic NetworksPorous PolymersThiol-Ene ChemistryAdsorbentSwellingTrivalentTetravalentArticle10.1007/s00289-021-03809-42-s2.0-85109352884